volume 29 issue 11 pages 7612-7621

Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process

Shangzhe Sun 1
Ming Zhao 2
Liang Cai 1
Shuai Zhang 1
Dewang Zeng 1
Rui Xiao 1
Publication typeJournal Article
Publication date2015-10-16
scimago Q1
wos Q1
SJR1.124
CiteScore9.5
Impact factor5.3
ISSN08870624, 15205029
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Abstract
The iron-based oxygen carrier with high oxygen transfer capacity has always been the key point in the chemical looping hydrogen generation (CLHG) process. In this study, CeO2-modified iron-based oxygen carriers with the porous reticular structure were prepared by the sol–gel method. Samples were tested in a thermogravimetric analyzer (TGA) and lab-scale fixed-bed reactor, respectively, to evaluate their capacities of hydrogen production and the resistance to carbon deposition or Fe3C formation. The effects of preparation conditions (CeO2 loading and [C6H8O7·H2O]/[PEG400] molar ratio) and experimental conditions (reducing atmosphere and temperature) on the physicochemical properties of CeO2-modified iron-based oxygen carriers were investigated. The initial screening test in TGA was done to select the samples with excellent reducibility and strong resistance to carbon deposition or Fe3C formation. Subsequent tests in the fixed-bed reactor were conducted to evaluate the redox characteristics and cyclic perfo...
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GOST |
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GOST Copy
Sun S. et al. Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process // Energy & Fuels. 2015. Vol. 29. No. 11. pp. 7612-7621.
GOST all authors (up to 50) Copy
Sun S., Zhao M., Cai L., Zhang S., Zeng D., Xiao R. Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process // Energy & Fuels. 2015. Vol. 29. No. 11. pp. 7612-7621.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.energyfuels.5b01444
UR - https://doi.org/10.1021/acs.energyfuels.5b01444
TI - Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process
T2 - Energy & Fuels
AU - Sun, Shangzhe
AU - Zhao, Ming
AU - Cai, Liang
AU - Zhang, Shuai
AU - Zeng, Dewang
AU - Xiao, Rui
PY - 2015
DA - 2015/10/16
PB - American Chemical Society (ACS)
SP - 7612-7621
IS - 11
VL - 29
SN - 0887-0624
SN - 1520-5029
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Sun,
author = {Shangzhe Sun and Ming Zhao and Liang Cai and Shuai Zhang and Dewang Zeng and Rui Xiao},
title = {Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process},
journal = {Energy & Fuels},
year = {2015},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.energyfuels.5b01444},
number = {11},
pages = {7612--7621},
doi = {10.1021/acs.energyfuels.5b01444}
}
MLA
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MLA Copy
Sun, Shangzhe, et al. “Performance of CeO2-Modified Iron-Based Oxygen Carrier in the Chemical Looping Hydrogen Generation Process.” Energy & Fuels, vol. 29, no. 11, Oct. 2015, pp. 7612-7621. https://doi.org/10.1021/acs.energyfuels.5b01444.