Energy & Fuels

, том 31 , издание 12 , страницы 13382-13391

Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content

Yulia Y. Borisova ¹

Elvira G Tazeeva ¹

Vladimir A. Mironov ¹

Dmitry N Borisov ¹

Svetlana G Yakubova ¹

Guzalia R Abilova ¹

Kirill Olegovich Sinyashin ¹

M R Yakubov ¹

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A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Street 8, Kazan 420088, Russian Federation

Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

Казанский научный центр РАН

Тип публикации: Journal Article

Дата публикации: 2017-11-16

American Chemical Society (ACS)

Energy & Fuels

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SJR: 1.124

CiteScore: 9.5

Impact factor: 5.3

ISSN: 08870624, 15205029

DOI: 10.1021/acs.energyfuels.7b02544

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General Chemical Engineering

Energy Engineering and Power Technology

Fuel Technology

Краткое описание

Extraction by N,N-dimethylformamide with further column chromatography allowed obtaining concentrate of vanadylporphyrins from asphaltenes of heavy sulfurous oils with high vanadium content. The prevailing types of vanadylporphyrins, their ratio, and molecular mass distribution were determined. The influence of obtained vanadylporphyrin concentrates on the stability of asphaltenes in the system “solvent/precipitator” was investigated. Kinetic studies using UV–vis spectroscopy have revealed that an increase in the content of vanadylporphyrins in asphaltenes leads to acceleration of their deposition from solution and destabilization of colloidal systems.

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Borisova Y. Y. et al. Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content // Energy & Fuels. 2017. Vol. 31. No. 12. pp. 13382-13391.

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Borisova Y. Y., Tazeeva E. G., Mironov V. A., Borisov D. N., Yakubova S. G., Abilova G. R., Sinyashin K. O., Yakubov M. R. Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content // Energy & Fuels. 2017. Vol. 31. No. 12. pp. 13382-13391.

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TY - JOUR

DO - 10.1021/acs.energyfuels.7b02544

UR - https://doi.org/10.1021/acs.energyfuels.7b02544

TI - Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content

T2 - Energy & Fuels

AU - Borisova, Yulia Y.

AU - Tazeeva, Elvira G

AU - Mironov, Vladimir A.

AU - Borisov, Dmitry N

AU - Yakubova, Svetlana G

AU - Abilova, Guzalia R

AU - Sinyashin, Kirill Olegovich

AU - Yakubov, M R

PY - 2017

DA - 2017/11/16

PB - American Chemical Society (ACS)

SP - 13382-13391

IS - 12

VL - 31

SN - 0887-0624

SN - 1520-5029

ER -

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@article{2017_Borisova,

author = {Yulia Y. Borisova and Elvira G Tazeeva and Vladimir A. Mironov and Dmitry N Borisov and Svetlana G Yakubova and Guzalia R Abilova and Kirill Olegovich Sinyashin and M R Yakubov},

title = {Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content},

journal = {Energy & Fuels},

year = {2017},

volume = {31},

publisher = {American Chemical Society (ACS)},

month = {nov},

url = {https://doi.org/10.1021/acs.energyfuels.7b02544},

number = {12},

pages = {13382--13391},

doi = {10.1021/acs.energyfuels.7b02544}

}

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Borisova, Yulia Y., et al. “Role of Vanadylporphyrins in the Flocculation and Sedimentation of Asphaltenes of Heavy Oils with High Vanadium Content.” Energy & Fuels, vol. 31, no. 12, Nov. 2017, pp. 13382-13391. https://doi.org/10.1021/acs.energyfuels.7b02544.