volume 32 issue 7 pages 7933-7942

Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC)

Publication typeJournal Article
Publication date2018-06-19
scimago Q1
wos Q1
SJR1.124
CiteScore9.5
Impact factor5.3
ISSN08870624, 15205029
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Abstract
In this study, the oxidation behavior and kinetics of linear alkanes (C20H42, C24H50, C30H62, C32H66, C36H74, C38H78, C50H102, and C54H110) were investigated by high pressure differential scanning calorimetry (HP-DSC). It turned out that only the exothermic peak of low-temperature oxidation (LTO) was observed during the oxidation process of these linear alkanes, which is different from the oxidation behavior of the crude oil. For the crude oil, two exothermic peaks were observed: LTO and high-temperature oxidation (HTO). This means that the linear alkanes barely contributed in the HTO reaction of crude oils. In addition, the exothermic peaks in the oxidation process of all these linear alkanes overlapped each other. They showed almost the same oxidation behavior in terms of the temperature range of reaction as well as the onset and peak temperatures. It seems that the oxidation behavior of the tested linear alkanes was independent of their carbon number. It was also found that increasing pressure resulted...
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GOST |
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GOST Copy
Yuan C. et al. Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC) // Energy & Fuels. 2018. Vol. 32. No. 7. pp. 7933-7942.
GOST all authors (up to 50) Copy
Yuan C., Emelianov D. A., Varfolomeev M. A., Pu W., Ushakova A. S. Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC) // Energy & Fuels. 2018. Vol. 32. No. 7. pp. 7933-7942.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.energyfuels.8b01401
UR - https://doi.org/10.1021/acs.energyfuels.8b01401
TI - Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC)
T2 - Energy & Fuels
AU - Yuan, Chengdong
AU - Emelianov, Dmitrii A
AU - Varfolomeev, Mikhail A.
AU - Pu, Wanfen
AU - Ushakova, Alexandra S
PY - 2018
DA - 2018/06/19
PB - American Chemical Society (ACS)
SP - 7933-7942
IS - 7
VL - 32
SN - 0887-0624
SN - 1520-5029
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Yuan,
author = {Chengdong Yuan and Dmitrii A Emelianov and Mikhail A. Varfolomeev and Wanfen Pu and Alexandra S Ushakova},
title = {Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC)},
journal = {Energy & Fuels},
year = {2018},
volume = {32},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.energyfuels.8b01401},
number = {7},
pages = {7933--7942},
doi = {10.1021/acs.energyfuels.8b01401}
}
MLA
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MLA Copy
Yuan, Chengdong, et al. “Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC).” Energy & Fuels, vol. 32, no. 7, Jun. 2018, pp. 7933-7942. https://doi.org/10.1021/acs.energyfuels.8b01401.