Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry
Тип публикации: Journal Article
Дата публикации: 2019-03-04
scimago Q1
wos Q1
БС1
SJR: 1.124
CiteScore: 9.5
Impact factor: 5.3
ISSN: 08870624, 15205029
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Краткое описание
In situ combustion (ISC) has been regarded as an efficient technique for the exploitation of heavy oil reserves. In this work, the thermal behavior of one heavy crude oil and the fractions of its saturates, aromatics, resins, and asphaltenes (SARA) during combustion was thoroughly investigated using high-pressure differential scanning calorimetry. Two typical isoconversional methods were adopted to determine the variation of activation energy (E) and frequency factor (Ar) versus conversion degree in the course of the reaction, followed by the evaluation of the reaction model, f(α), via the master plot method. The results indicated that the heavy oil encountered larger thermal release caused by low-temperature oxidation (LTO) reactions rather than high-temperature oxidation (HTO) reactions, suggesting that appreciable heat could be available within the low-temperature range. Saturates showed a notably apparent heat release in the LTO reactions. For aromatics, the exothermic effect at the LTO stage was appa...
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Zhao S. et al. Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry // Energy & Fuels. 2019. Vol. 33. No. 4. pp. 3176-3186.
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Zhao S., Pu W., Yuan C., Peng X., ZHANG J., Wang L., Emelianov D. A. Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry // Energy & Fuels. 2019. Vol. 33. No. 4. pp. 3176-3186.
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TY - JOUR
DO - 10.1021/acs.energyfuels.9b00399
UR - https://pubs.acs.org/doi/10.1021/acs.energyfuels.9b00399
TI - Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry
T2 - Energy & Fuels
AU - Zhao, Shuai
AU - Pu, Wanfen
AU - Yuan, Chengdong
AU - Peng, Xiaoqiang
AU - ZHANG, JIZHOU
AU - Wang, Liangliang
AU - Emelianov, Dmitrii A
PY - 2019
DA - 2019/03/04
PB - American Chemical Society (ACS)
SP - 3176-3186
IS - 4
VL - 33
SN - 0887-0624
SN - 1520-5029
ER -
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@article{2019_Zhao,
author = {Shuai Zhao and Wanfen Pu and Chengdong Yuan and Xiaoqiang Peng and JIZHOU ZHANG and Liangliang Wang and Dmitrii A Emelianov},
title = {Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry},
journal = {Energy & Fuels},
year = {2019},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.energyfuels.9b00399},
number = {4},
pages = {3176--3186},
doi = {10.1021/acs.energyfuels.9b00399}
}
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MLA
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Zhao, Shuai, et al. “Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry.” Energy & Fuels, vol. 33, no. 4, Mar. 2019, pp. 3176-3186. https://pubs.acs.org/doi/10.1021/acs.energyfuels.9b00399.