Energy & Fuels

, volume 33 , issue 4 , pages 3176-3186

Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry

Shuai Zhao ¹

Wanfen Pu ^{1, 2}

Chengdong Yuan ^{1, 2}

Xiaoqiang Peng ³

Jizhou Zhang ³

Liang Liang Wang ¹

Dmitrii A Emelianov ²

Hide authors affiliations Show authors affiliations: 3 affiliations

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, People’s Republic of China |

Department of Physical Chemistry, Kazan Federal University, Kremlevskaya Street 18, Kazan 420008, Russia |

Research Institute of Experimental and Detection, Petrochina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, People’s Republic of China |

Publication type: Journal Article

Publication date: 2019-03-04

American Chemical Society (ACS)

Energy & Fuels

scimago Q1

wos Q1

SJR: 1.124

CiteScore: 9.5

Impact factor: 5.3

ISSN: 08870624, 15205029

DOI: 10.1021/acs.energyfuels.9b00399

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General Chemical Engineering

Energy Engineering and Power Technology

Fuel Technology

Abstract

In situ combustion (ISC) has been regarded as an efficient technique for the exploitation of heavy oil reserves. In this work, the thermal behavior of one heavy crude oil and the fractions of its saturates, aromatics, resins, and asphaltenes (SARA) during combustion was thoroughly investigated using high-pressure differential scanning calorimetry. Two typical isoconversional methods were adopted to determine the variation of activation energy (E) and frequency factor (Ar) versus conversion degree in the course of the reaction, followed by the evaluation of the reaction model, f(α), via the master plot method. The results indicated that the heavy oil encountered larger thermal release caused by low-temperature oxidation (LTO) reactions rather than high-temperature oxidation (HTO) reactions, suggesting that appreciable heat could be available within the low-temperature range. Saturates showed a notably apparent heat release in the LTO reactions. For aromatics, the exothermic effect at the LTO stage was appa...

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3 citations

Emelianov Dmitrii

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65 publications, 1 180 citations

h-index: 20

Kazan Federal University

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GOST |

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GOST Copy

Zhao S. et al. Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry // Energy & Fuels. 2019. Vol. 33. No. 4. pp. 3176-3186.

GOST all authors (up to 50) Copy

Zhao S., Pu W., Yuan C., Peng X., Zhang J., Wang L. L., Emelianov D. A. Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry // Energy & Fuels. 2019. Vol. 33. No. 4. pp. 3176-3186.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acs.energyfuels.9b00399

UR - https://doi.org/10.1021/acs.energyfuels.9b00399

TI - Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry

T2 - Energy & Fuels

AU - Zhao, Shuai

AU - Pu, Wanfen

AU - Yuan, Chengdong

AU - Peng, Xiaoqiang

AU - Zhang, Jizhou

AU - Wang, Liang Liang

AU - Emelianov, Dmitrii A

PY - 2019

DA - 2019/03/04

PB - American Chemical Society (ACS)

SP - 3176-3186

IS - 4

VL - 33

SN - 0887-0624

SN - 1520-5029

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Zhao,

author = {Shuai Zhao and Wanfen Pu and Chengdong Yuan and Xiaoqiang Peng and Jizhou Zhang and Liang Liang Wang and Dmitrii A Emelianov},

title = {Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry},

journal = {Energy & Fuels},

year = {2019},

volume = {33},

publisher = {American Chemical Society (ACS)},

month = {mar},

url = {https://doi.org/10.1021/acs.energyfuels.9b00399},

number = {4},

pages = {3176--3186},

doi = {10.1021/acs.energyfuels.9b00399}

}

MLA

Cite this

MLA Copy

Zhao, Shuai, et al. “Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry.” Energy & Fuels, vol. 33, no. 4, Mar. 2019, pp. 3176-3186. https://doi.org/10.1021/acs.energyfuels.9b00399.

Publisher

American Chemical Society (ACS)

Journal

Energy & Fuels

scimago Q1

wos Q1

SJR

1.124

CiteScore

9.5

Impact factor

5.3

ISSN

08870624 (Print)

15205029 (Electronic)

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