Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids
Rishat I Aminov
1
,
Ravil I Khusnutdinov
1
Publication type: Journal Article
Publication date: 2021-08-23
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
A new method was developed for hydrogenation of unsaturated hexacyclic norbornadiene dimers, exo-exo-, exo-endo-, endo-exo-, and endo-endo- hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes, using sulfuric acid (98%), giving pentacyclo[8.2.1.15,8.02,9.03,7]tetradecanes, which were subjected to skeletal rearrangement under the action of ionic liquids to form diamantane in up to 84% yield.
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Total citations:
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Citations from 2025:
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Aminov R. I., Khusnutdinov R. I. Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids // Industrial & Engineering Chemistry Research. 2021. Vol. 60. No. 34. pp. 12776-12782.
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Aminov R. I., Khusnutdinov R. I. Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids // Industrial & Engineering Chemistry Research. 2021. Vol. 60. No. 34. pp. 12776-12782.
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TY - JOUR
DO - 10.1021/acs.iecr.1c02082
UR - https://doi.org/10.1021/acs.iecr.1c02082
TI - Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids
T2 - Industrial & Engineering Chemistry Research
AU - Aminov, Rishat I
AU - Khusnutdinov, Ravil I
PY - 2021
DA - 2021/08/23
PB - American Chemical Society (ACS)
SP - 12776-12782
IS - 34
VL - 60
SN - 0888-5885
SN - 1520-5045
ER -
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BibTex (up to 50 authors)
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@article{2021_Aminov,
author = {Rishat I Aminov and Ravil I Khusnutdinov},
title = {Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids},
journal = {Industrial & Engineering Chemistry Research},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.iecr.1c02082},
number = {34},
pages = {12776--12782},
doi = {10.1021/acs.iecr.1c02082}
}
Cite this
MLA
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Aminov, Rishat I., and Ravil I Khusnutdinov. “Synthesis of Polycyclic Hydrocarbons C14H20 by Hydrogenation of exo–exo-, exo–endo-, endo–exo-, and endo–endo-Hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-enes with H2SO4 and Isomerization of the Products to Diamantane Induced by Ionic Liquids.” Industrial & Engineering Chemistry Research, vol. 60, no. 34, Aug. 2021, pp. 12776-12782. https://doi.org/10.1021/acs.iecr.1c02082.
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