Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants
Xing Zhang
1
,
Lianhua Shen
1
,
Yuhong Luo
1
,
Rongpei Jiang
1
,
Haiyun Sun
1
,
Jiuzhou Liu
1, 2
,
Tao Fang
1
,
Huili Fan
2
,
Zhaoyang Liu
1
1
Beijing Institute of Aerospace Testing Technology, Beijing Key Laboratory of Research and Application for Aerospace
Green Propellants, Beijing 100074, China
|
Publication type: Journal Article
Publication date: 2017-03-08
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
1,5-Diazabicyclo[3.1.0]hexane type compounds (DABHCs) were found as promising liquid hypergolic compounds. The synthesis process and purification of DABHCs, 1,5-diazabicyclo[3.1.0]hexane (DABH), 6-methyl-1,5-diazabicyclo[3.1.0]hexane (MDABH), 6-ethyl-1,5-diazabicyclo[3.1.0]hexane (EDABH), and 6,6-dimethyl-1,5-diazabicyclo[3.1.0]hexane (DDABH) were optimized. The densities of DABHCs were over 1.0 g/mL, and the viscosities of DABHCs were about 2.40–2.63 mPa·s. The boiling points of DABHCs exhibited that they were less volatile, and the freezing points of DABHCs varied considerably for different alkylation. The LD50 predicted values of DABHCs were within 1605.62–4865.43 mg/kg, which demonstrated that DABHCs were grade IV, slightly poisonous, or grade V, nontoxic, compounds according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). In addition, the heats of formation of DABHCs were calculated as 129.2–276.2 kJ/mol, higher than those of monomethyl hydrazine, unsymmetrical di...
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Citations from 2025:
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GOST
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Zhang X. et al. Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants // Industrial & Engineering Chemistry Research. 2017. Vol. 56. No. 11. pp. 2883-2888.
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Zhang X., Shen L., Luo Y., Jiang R., Sun H., Liu J., Fang T., Fan H., Liu Z. Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants // Industrial & Engineering Chemistry Research. 2017. Vol. 56. No. 11. pp. 2883-2888.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.iecr.6b04842
UR - https://doi.org/10.1021/acs.iecr.6b04842
TI - Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants
T2 - Industrial & Engineering Chemistry Research
AU - Zhang, Xing
AU - Shen, Lianhua
AU - Luo, Yuhong
AU - Jiang, Rongpei
AU - Sun, Haiyun
AU - Liu, Jiuzhou
AU - Fang, Tao
AU - Fan, Huili
AU - Liu, Zhaoyang
PY - 2017
DA - 2017/03/08
PB - American Chemical Society (ACS)
SP - 2883-2888
IS - 11
VL - 56
SN - 0888-5885
SN - 1520-5045
ER -
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@article{2017_Zhang,
author = {Xing Zhang and Lianhua Shen and Yuhong Luo and Rongpei Jiang and Haiyun Sun and Jiuzhou Liu and Tao Fang and Huili Fan and Zhaoyang Liu},
title = {Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants},
journal = {Industrial & Engineering Chemistry Research},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.iecr.6b04842},
number = {11},
pages = {2883--2888},
doi = {10.1021/acs.iecr.6b04842}
}
Cite this
MLA
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Zhang, Xing, et al. “Synthesis and Ignition Properties Research of 1,5-Diazabicyclo[3.1.0]Hexane Type Compounds as Potential Green Hypergolic Propellants.” Industrial & Engineering Chemistry Research, vol. 56, no. 11, Mar. 2017, pp. 2883-2888. https://doi.org/10.1021/acs.iecr.6b04842.