volume 56 issue 14 pages 3937-3946

Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks

Publication typeJournal Article
Publication date2017-04-03
scimago Q1
wos Q2
SJR0.828
CiteScore6.7
Impact factor3.9
ISSN08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
Novel biobased multiblock polyesters poly(2,5-furandimethylene succinate)-b-poly(butylene succinate) (PFS-PBS) containing PFS and PBS blocks were synthesized in a full composition range via chain-extension reaction of dihydroxyl terminated poly(2,5-furandimethylene succinate) (HO-PFS-OH) and poly(butylene succinate) (HO-PBS-OH) prepolymers. High molecular weight polyesters were obtained, and the stability of double bonds in 2,5-bis(hydroxymethyl)furan was guaranteed via this preparation procedure. The obtained copolyesters were characterized with 1H NMR, gel permeation chromatography, differential scanning calorimetry, thermogravimetric analysis, polarized optical microscopy, wide-angle X-ray diffraction, and the mechanical properties were also investigated. No transesterfication reaction happened during chain-extension reaction, and the expected multiblock chemical structure was obtained. The PBS block is crystallizable, while the PFS block is nearly amorphous. Crystallization temperature and degree of c...
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GOST |
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GOST Copy
Zhang Y. et al. Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks // Industrial & Engineering Chemistry Research. 2017. Vol. 56. No. 14. pp. 3937-3946.
GOST all authors (up to 50) Copy
Zhang Y., Li T., Xie Z., Han J., Xu J., Guo B. Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks // Industrial & Engineering Chemistry Research. 2017. Vol. 56. No. 14. pp. 3937-3946.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.iecr.7b00516
UR - https://doi.org/10.1021/acs.iecr.7b00516
TI - Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks
T2 - Industrial & Engineering Chemistry Research
AU - Zhang, Yang
AU - Li, Ting
AU - Xie, Zhining
AU - Han, Jiarui
AU - Xu, Jun
AU - Guo, Bao-Hua
PY - 2017
DA - 2017/04/03
PB - American Chemical Society (ACS)
SP - 3937-3946
IS - 14
VL - 56
SN - 0888-5885
SN - 1520-5045
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Zhang,
author = {Yang Zhang and Ting Li and Zhining Xie and Jiarui Han and Jun Xu and Bao-Hua Guo},
title = {Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks},
journal = {Industrial & Engineering Chemistry Research},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.iecr.7b00516},
number = {14},
pages = {3937--3946},
doi = {10.1021/acs.iecr.7b00516}
}
MLA
Cite this
MLA Copy
Zhang, Yang, et al. “Synthesis and Properties of Biobased Multiblock Polyesters Containing Poly(2,5-furandimethylene succinate) and Poly(butylene succinate) Blocks.” Industrial & Engineering Chemistry Research, vol. 56, no. 14, Apr. 2017, pp. 3937-3946. https://doi.org/10.1021/acs.iecr.7b00516.