Industrial & Engineering Chemistry Research, volume 59, issue 3, pages 1183-1192
Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol
M M Buitelaar
1
,
E Van Daatselaar
1
,
D G Van Teijlingen
1
,
H I Stokvis
1
,
J D Wendt
1
,
R J De Sousa Ribeiro
1
,
A M M Brooks
1
,
E C Kamphuis
1
,
S Lopez Montoya
1
,
J C Van Putten
1
,
A.G.J van der Ham
1
,
H. van den Berg
1
,
Jean W. Lange
1, 2
2
Shell Technology Center Amsterdam, Grasweg 31, 1031 HW Amsterdam, Netherlands
|
Publication type: Journal Article
Publication date: 2019-12-20
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.2
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
The chemical industry is currently facing the challenge of developing biobased production processes suitable for a more sustainable chemical industry. Acrylic acid produced from monopropylene glycol is a good candidate to become a cost-competitive and sustainable platform chemical. The propylene glycol price is expected to drop due to the expected abundance of propylene glycol as a sugar hydrogenolysis byproduct, which is required to make the conversion to acrylic acid cost-competitive. Two different processes for the conversion of propylene glycol to acrylic acid are evaluated in this work, either by (1) low temperature oxidation of propylene glycol to lactic acid and high temperature dehydration to acrylic acid or by (2) high temperature dehydration of propylene glycol to allyl alcohol and further high temperature oxidation to acrylic acid. Liquid-liquid extraction was found to be a key operation in both production processes. At similar overall yields, the allyl alcohol route appears inherently favored, as a result of the opportunity to integrate the reaction heat available at high temperature. To conclude, the price of propylene glycol has to drop by 45-55% to make the biobased production of acrylic acid from propylene glycol economically feasible.
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Buitelaar M. M. et al. Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol // Industrial & Engineering Chemistry Research. 2019. Vol. 59. No. 3. pp. 1183-1192.
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Buitelaar M. M., Van Daatselaar E., Van Teijlingen D. G., Stokvis H. I., Wendt J. D., De Sousa Ribeiro R. J., Brooks A. M. M., Kamphuis E. C., Lopez Montoya S., Van Putten J. C., van der Ham A., van den Berg H., Lange J. W. Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol // Industrial & Engineering Chemistry Research. 2019. Vol. 59. No. 3. pp. 1183-1192.
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TY - JOUR
DO - 10.1021/acs.iecr.9b04334
UR - https://doi.org/10.1021/acs.iecr.9b04334
TI - Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol
T2 - Industrial & Engineering Chemistry Research
AU - Buitelaar, M M
AU - Van Daatselaar, E
AU - Van Teijlingen, D G
AU - Stokvis, H I
AU - De Sousa Ribeiro, R J
AU - Brooks, A M M
AU - Kamphuis, E C
AU - Lopez Montoya, S
AU - Van Putten, J C
AU - van der Ham, A.G.J
AU - van den Berg, H.
AU - Wendt, J D
AU - Lange, Jean W.
PY - 2019
DA - 2019/12/20
PB - American Chemical Society (ACS)
SP - 1183-1192
IS - 3
VL - 59
SN - 0888-5885
SN - 1520-5045
ER -
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BibTex
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@article{2019_Buitelaar,
author = {M M Buitelaar and E Van Daatselaar and D G Van Teijlingen and H I Stokvis and R J De Sousa Ribeiro and A M M Brooks and E C Kamphuis and S Lopez Montoya and J C Van Putten and A.G.J van der Ham and H. van den Berg and J D Wendt and Jean W. Lange},
title = {Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol},
journal = {Industrial & Engineering Chemistry Research},
year = {2019},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.iecr.9b04334},
number = {3},
pages = {1183--1192},
doi = {10.1021/acs.iecr.9b04334}
}
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Buitelaar, M. M., et al. “Process Designs for Converting Propylene Glycol to Acrylic Acid via Lactic Acid and Allyl Alcohol.” Industrial & Engineering Chemistry Research, vol. 59, no. 3, Dec. 2019, pp. 1183-1192. https://doi.org/10.1021/acs.iecr.9b04334.