A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate.
Chen Wei
1
,
Boxun Sun
1
,
Zifeng Zhao
1
,
Zelun Cai
1
,
Jiajia Liu
1
,
Yu Tan
1
,
Huibo Wei
2
,
Zhiwei Liu
1
,
Zuqiang Bian
1
,
Chunhui Huang
1
1
2
Jiangsu JITRI Molecular Engineering Institute Co., Ltd., 88 Xianshi Road, Changshu 215500, China
|
Тип публикации: Journal Article
Дата публикации: 2020-06-09
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32515946
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
We report a novel family of lanthanide complexes Ln(DPPOP)3 (Ln = Pr, Nd, Sm, Eu, Tb, Dy, Er, and Yb) employing anionic tridentate (O∧N∧O) ligand 6-(diphenylphosphoryl)picolinate (DPPOP). Crystal structures of the complexes reveal that each lanthanide ion is nine-coordinated by three tridentate ligands. In the crystals, 1D channels are found, which can absorb and eliminate water reversibly. DPPOP possesses high triplet energy and can sensitize a series of lanthanide ions. An energy transfer mechanism is proposed through the higher excited states of the lanthanide ions. In the solid state, remarkably high quantum yields in the visible range are obtained: 81% for Eu(III), 97% for Tb(III), 13% for Dy(III), and 4% for Sm(III) complex.
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ГОСТ
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Wei C. et al. A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate. // Inorganic Chemistry. 2020. Vol. 59. No. 13. pp. 8800-8808.
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Wei C., Sun B., Zhao Z., Cai Z., Liu J., Tan Yu., Wei H., Liu Z., Bian Z., Huang C. A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate. // Inorganic Chemistry. 2020. Vol. 59. No. 13. pp. 8800-8808.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c00444
UR - https://doi.org/10.1021/acs.inorgchem.0c00444
TI - A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate.
T2 - Inorganic Chemistry
AU - Wei, Chen
AU - Sun, Boxun
AU - Zhao, Zifeng
AU - Cai, Zelun
AU - Liu, Jiajia
AU - Tan, Yu
AU - Wei, Huibo
AU - Liu, Zhiwei
AU - Bian, Zuqiang
AU - Huang, Chunhui
PY - 2020
DA - 2020/06/09
PB - American Chemical Society (ACS)
SP - 8800-8808
IS - 13
VL - 59
PMID - 32515946
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Wei,
author = {Chen Wei and Boxun Sun and Zifeng Zhao and Zelun Cai and Jiajia Liu and Yu Tan and Huibo Wei and Zhiwei Liu and Zuqiang Bian and Chunhui Huang},
title = {A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate.},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.inorgchem.0c00444},
number = {13},
pages = {8800--8808},
doi = {10.1021/acs.inorgchem.0c00444}
}
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MLA
Скопировать
Wei, Chen, et al. “A Family of Highly Emissive Lanthanide Complexes Constructed with 6-(Diphenylphosphoryl)picolinate..” Inorganic Chemistry, vol. 59, no. 13, Jun. 2020, pp. 8800-8808. https://doi.org/10.1021/acs.inorgchem.0c00444.