Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70
Publication type: Journal Article
Publication date: 2020-07-10
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32648746
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The isolated-pentagon-rule (IPR) D5h-C70 fullerene is least susceptible to skeletal transformations in comparison with higher fullerenes and even C60. A cage transformation in IPR C70 via a one-step Stone-Wales rearrangement was accomplished by high-temperature (440 °C) ampule chlorination with SbCl5. Subsequent dechlorination at 450 °C, followed by high-performance liquid chromatography separation, allowed the isolation of non-IPR C70Cl6 and C70Cl8. X-ray diffraction study revealed the presence of an unprecedented C70 carbon cage, possessing two pairs of fused pentagons and the chlorination patterns located on one cage hemisphere. A high energetic and thermal stability of both non-IPR chlorides was also confirmed by theoretical calculations of formation energies. Pathways of skeletal transformations of IPR C70 in comparison with those in C60 are discussed.
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Tamm N. B. et al. Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70 // Inorganic Chemistry. 2020. Vol. 59. No. 15. pp. 10400-10403.
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Tamm N. B., Brotsman V. A., Markov V., Troyanov S. Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70 // Inorganic Chemistry. 2020. Vol. 59. No. 15. pp. 10400-10403.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01510
UR - https://doi.org/10.1021/acs.inorgchem.0c01510
TI - Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70
T2 - Inorganic Chemistry
AU - Tamm, Nadezhda B
AU - Brotsman, Victor A
AU - Markov, Vitaliy
AU - Troyanov, Sergey
PY - 2020
DA - 2020/07/10
PB - American Chemical Society (ACS)
SP - 10400-10403
IS - 15
VL - 59
PMID - 32648746
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2020_Tamm,
author = {Nadezhda B Tamm and Victor A Brotsman and Vitaliy Markov and Sergey Troyanov},
title = {Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.inorgchem.0c01510},
number = {15},
pages = {10400--10403},
doi = {10.1021/acs.inorgchem.0c01510}
}
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MLA
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Tamm, Nadezhda B., et al. “Fused-Pentagon C70Cl6 and C70Cl8 Obtained via Chlorination-Promoted Skeletal Transformation of IPR C70.” Inorganic Chemistry, vol. 59, no. 15, Jul. 2020, pp. 10400-10403. https://doi.org/10.1021/acs.inorgchem.0c01510.