Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity
S.V. Adichtchev
2
,
V. V. Atuchin
3, 4, 5
,
Bair G. Bazarov
1, 6
,
Jibzema Bazarova
1
,
Natalia Kuratieva
7, 8
,
Aleksandr S. Oreshonkov
9, 10
,
Natalia V Pervukhina
4, 7
,
Publication type: Journal Article
Publication date: 2020-08-12
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32805991
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The phase relations in the subsolidus region of the Tl2MoO4-Bi2(MoO4)3-Hf(MoO4)2 system were studied with the "intersecting cuts" method. The formation of the novel ternary molybdate Tl5BiHf(MoO4)6 is found in this ternary system. The compound has a phase transition at Tpt = 731 K (ΔH = -3.15 J/g) and melts at Tm = 871 K (ΔH = -41.71 J/g), as determined by a thermal analysis. Tl5BiHf(MoO4)6 single crystals were obtained by the spontaneous nucleation method. The crystal structure of Tl5BiHf(MoO4)6 was revealed by structure analysis methods. This molybdate crystallizes in the trigonal space group R3̅c with the unit cell parameters a = 10.6801(4) Å, c = 38.5518(14) Å, V = 3808.3(2) Å3, and Z = 6. The vibrational characteristics of Tl5BiHf(MoO4)6 were determined by Raman spectroscopy. The Tl5BiHf(MoO4)6 conductivity was measured at frequencies of 0.1, 1.0, and 10 kHz in the temperature range of 293-773 K; in this temperature range, the conductivity level was 10-12-10-7 S/cm.
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12
Total citations:
12
Citations from 2024:
4
(33%)
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Grossman V. et al. Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity // Inorganic Chemistry. 2020. Vol. 59. No. 17. pp. 12681-12689.
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Grossman V., Adichtchev S., Atuchin V. V., Bazarov B. G., Bazarova J., Kuratieva N., Oreshonkov A. S., Pervukhina N. V., Surovtsev N. Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity // Inorganic Chemistry. 2020. Vol. 59. No. 17. pp. 12681-12689.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01762
UR - https://doi.org/10.1021/acs.inorgchem.0c01762
TI - Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity
T2 - Inorganic Chemistry
AU - Grossman, Victoria
AU - Adichtchev, S.V.
AU - Atuchin, V. V.
AU - Bazarov, Bair G.
AU - Bazarova, Jibzema
AU - Kuratieva, Natalia
AU - Oreshonkov, Aleksandr S.
AU - Pervukhina, Natalia V
AU - Surovtsev, N.V.
PY - 2020
DA - 2020/08/12
PB - American Chemical Society (ACS)
SP - 12681-12689
IS - 17
VL - 59
PMID - 32805991
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Grossman,
author = {Victoria Grossman and S.V. Adichtchev and V. V. Atuchin and Bair G. Bazarov and Jibzema Bazarova and Natalia Kuratieva and Aleksandr S. Oreshonkov and Natalia V Pervukhina and N.V. Surovtsev},
title = {Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.inorgchem.0c01762},
number = {17},
pages = {12681--12689},
doi = {10.1021/acs.inorgchem.0c01762}
}
Cite this
MLA
Copy
Grossman, Victoria, et al. “Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity.” Inorganic Chemistry, vol. 59, no. 17, Aug. 2020, pp. 12681-12689. https://doi.org/10.1021/acs.inorgchem.0c01762.