Inorganic Chemistry, volume 59, issue 20, pages 14819-14826
Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2
Maxim Bykov
1, 2
,
Kelin R Tasca
1, 2
,
Iskander Batyrev
3
,
Dean Smith
4
,
K. Glazyrin
5
,
Stella Chariton
6
,
MOHAMMAD MAHMOOD
1
,
2
The Earth and Planets Laboratory, Carnegie Institution for Science, Washington, DC 20015, United States
|
3
U.S. Army Research Laboratory, RDRL-WML-B, Aberdeen Proving Ground, Maryland 21005, United States
|
4
Publication type: Journal Article
Publication date: 2020-10-01
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
With the exception of lithium, alkali metals do not react with elemental nitrogen either at ambient conditions or at elevated temperatures, requiring the search for alternative synthetic routes to their nitrogen-containing compounds. Here using a controlled decomposition of sodium azide (NaN3) at high pressure conditions, we synthesize two novel compounds, Na3(N2)4 and NaN2, both containing dinitrogen anions. NaN2 synthesized at 4 GPa might be the common intermediate in high-pressure solid-state metathesis reactions, where NaN3 is used as a source of nitrogen, while Na3(N2)4 opens a new class of compounds, where [N2] units accommodate a noninteger formal charge of 0.75-. This finding can dramatically extend the expected compositions in other group 1 and 2 metal-nitrogen systems. Electronic structure calculations show the metallic character for both compounds.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bykov M. et al. Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2 // Inorganic Chemistry. 2020. Vol. 59. No. 20. pp. 14819-14826.
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Bykov M., Tasca K. R., Batyrev I., Smith D., Glazyrin K., Chariton S., MAHMOOD M., Goncharov A. Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2 // Inorganic Chemistry. 2020. Vol. 59. No. 20. pp. 14819-14826.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01863
UR - https://doi.org/10.1021/acs.inorgchem.0c01863
TI - Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2
T2 - Inorganic Chemistry
AU - Tasca, Kelin R
AU - MAHMOOD, MOHAMMAD
AU - Bykov, Maxim
AU - Batyrev, Iskander
AU - Smith, Dean
AU - Glazyrin, K.
AU - Chariton, Stella
AU - Goncharov, Alexander
PY - 2020
DA - 2020/10/01 00:00:00
PB - American Chemical Society (ACS)
SP - 14819-14826
IS - 20
VL - 59
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Bykov,
author = {Kelin R Tasca and MOHAMMAD MAHMOOD and Maxim Bykov and Iskander Batyrev and Dean Smith and K. Glazyrin and Stella Chariton and Alexander Goncharov},
title = {Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.0c01863},
number = {20},
pages = {14819--14826},
doi = {10.1021/acs.inorgchem.0c01863}
}
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Bykov, Maxim, et al. “Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na3(N2)4 and NaN2.” Inorganic Chemistry, vol. 59, no. 20, Oct. 2020, pp. 14819-14826. https://doi.org/10.1021/acs.inorgchem.0c01863.