American Chemical Society (ACS)
Inorganic Chemistry
,  том 59 ,  издание 24 ,  страницы 17866-17869

Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives.

Тип публикации: Journal Article
Дата публикации: 2020-12-08
American Chemical Society (ACS)
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The family of experimentally confirmed isolated-pentagon-rule (IPR) isomers of C96 fullerene is extended by trifluoromethylation of a C96 fraction of the fullerene soot, high-performance liquid chromatography separation of CF3 derivatives, and a single-crystal X-ray diffraction study of C96(CF3)n compounds with the use of synchrotron radiation. New cage isomers were revealed in C96(94)(CF3)18/20 and C96(182)(CF3)18 compounds, whereas isomer C96(181), previously known in the adduct with nickel porphyrinate, was confirmed in C96(181)(CF3)18/20 derivatives. Common and special features of the addition patterns of CF3 groups on C96 carbon cages are discussed in more detail. The investigated isomers belong to the most stable C2-C96(181) and slightly less stable C1-C96(94) and C2-C96(182) among the altogether 15 experimentally confirmed IPR isomers of C96 fullerene.
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Tamm N. B. et al. Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives. // Inorganic Chemistry. 2020. Vol. 59. No. 24. pp. 17866-17869.
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Tamm N. B., Guan R., Yang S., Sidorov L. N., Troyanov S. Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives. // Inorganic Chemistry. 2020. Vol. 59. No. 24. pp. 17866-17869.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c02919
UR - https://doi.org/10.1021/acs.inorgchem.0c02919
TI - Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives.
T2 - Inorganic Chemistry
AU - Tamm, Nadezhda B
AU - Guan, Runnan
AU - Yang, Shangfeng
AU - Sidorov, Lev N.
AU - Troyanov, Sergey
PY - 2020
DA - 2020/12/08
PB - American Chemical Society (ACS)
SP - 17866-17869
IS - 24
VL - 59
PMID - 33290050
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Tamm,
author = {Nadezhda B Tamm and Runnan Guan and Shangfeng Yang and Lev N. Sidorov and Sergey Troyanov},
title = {Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives.},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.inorgchem.0c02919},
number = {24},
pages = {17866--17869},
doi = {10.1021/acs.inorgchem.0c02919}
}
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Tamm, Nadezhda B., et al. “Three Isolated-Pentagon-Rule Isomers of C96 Fullerene Isolated as Trifluoromethyl Derivatives..” Inorganic Chemistry, vol. 59, no. 24, Dec. 2020, pp. 17866-17869. https://doi.org/10.1021/acs.inorgchem.0c02919.