Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate
2
4
Singapore-HUJ Alliance for Research and Enterprise (SHARE), NEW-CREATE Phase II Campus for Research Excellence and Technological Enterprise (CREATE), Singapore 138602, Singapore
|
Publication type: Journal Article
Publication date: 2020-12-07
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
33285066
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A breakthrough "superoxide colloidal solution route" for low-temperature synthesis of barium and strontium stannate perovskites and their doped analogues was recently introduced. The synthesis starts from hydrogen peroxide-rich stannate solutions and yields a so-called "crystalline superoxide molecular cluster" that is converted by low temperature (<300 °C) to the respective perovskites. In this paper, the so-called "crystalline superoxide molecular cluster" is identified as a superoxide-free, barium trihydroxo(hydroperoxo)peroxostannate, BaSn(OH)3(OOH)(OO) phase (BHHPS). EPR and Raman spectroscopy studies reveal the absence of superoxide in this crystalline phase. FTIR of the deuterated sample, 119Sn NMR, and elemental analysis uncovered the empirical formula, H4O7SnBa with two peroxides per each tin element. Rietveld refinement of the XRD confirms the BHHPS cubic phase with replacement of the perovskite oxygen atoms by the OH- and OOH-ligands and peroxobridging groups.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Mendeleev Communications
2 publications, 15.38%
|
|
|
Inorganic Chemistry
2 publications, 15.38%
|
|
|
Journal of Alloys and Compounds
1 publication, 7.69%
|
|
|
Nanomaterials and Energy
1 publication, 7.69%
|
|
|
Materials Today Chemistry
1 publication, 7.69%
|
|
|
Journal of Composites Science
1 publication, 7.69%
|
|
|
Journal of Solid State Chemistry
1 publication, 7.69%
|
|
|
Current Materials Science
1 publication, 7.69%
|
|
|
Structural Chemistry
1 publication, 7.69%
|
|
|
e-Journal of Surface Science and Nanotechnology
1 publication, 7.69%
|
|
|
International Journal of Hydrogen Energy
1 publication, 7.69%
|
|
|
1
2
|
Publishers
|
1
2
3
4
|
|
|
Elsevier
4 publications, 30.77%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
2 publications, 15.38%
|
|
|
American Chemical Society (ACS)
2 publications, 15.38%
|
|
|
Thomas Telford
1 publication, 7.69%
|
|
|
MDPI
1 publication, 7.69%
|
|
|
Bentham Science Publishers Ltd.
1 publication, 7.69%
|
|
|
Springer Nature
1 publication, 7.69%
|
|
|
The Surface Science Society of Japan
1 publication, 7.69%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
13
Total citations:
13
Citations from 2024:
4
(30%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Medvedev A. G. et al. Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate // Inorganic Chemistry. 2020. Vol. 59. No. 24. pp. 18358-18365.
GOST all authors (up to 50)
Copy
Medvedev A. G., Mikhaylov A., Shames A. I., Ilyukhin A. B., Churakov A. V., Grishanov D. A., Melnik E. A., Tripolskaya T. A., Lev O., Prikhodchenko P. V. Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate // Inorganic Chemistry. 2020. Vol. 59. No. 24. pp. 18358-18365.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.0c02993
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02993
TI - Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate
T2 - Inorganic Chemistry
AU - Medvedev, Alexander G.
AU - Mikhaylov, Alexey
AU - Shames, Alexander I.
AU - Ilyukhin, Andrey B.
AU - Churakov, Andrei V.
AU - Grishanov, Dmitry A
AU - Melnik, E A
AU - Tripolskaya, Tatiana A
AU - Lev, Ovadia
AU - Prikhodchenko, Petr V.
PY - 2020
DA - 2020/12/07
PB - American Chemical Society (ACS)
SP - 18358-18365
IS - 24
VL - 59
PMID - 33285066
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Medvedev,
author = {Alexander G. Medvedev and Alexey Mikhaylov and Alexander I. Shames and Andrey B. Ilyukhin and Andrei V. Churakov and Dmitry A Grishanov and E A Melnik and Tatiana A Tripolskaya and Ovadia Lev and Petr V. Prikhodchenko},
title = {Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02993},
number = {24},
pages = {18358--18365},
doi = {10.1021/acs.inorgchem.0c02993}
}
Cite this
MLA
Copy
Medvedev, Alexander G., et al. “Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate.” Inorganic Chemistry, vol. 59, no. 24, Dec. 2020, pp. 18358-18365. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02993.