Complexes of Metal Halides with Unreduced o-(Imino)quinones.
Publication type: Journal Article
Publication date: 2021-08-02
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
34339176
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of complexes of metal halides with unreduced quinone-type ligands have been synthesized and characterized in detail. The 3,6-di-tert-butyl-o-benzoquinone (1) and 4,6-di-tert-butyl-N-aryl-substituted o-iminobenzoquinones (2-5) (aryl is 2,6-dimethylphenyl in 2, 2-methyl-6-ethylphenyl in 3, 2,6-diethylphenyl in 4, and 2,6-diisopropylphenyl in 5) were used to obtain the molecular complexes with metal 12 group halides as well as with indium(III) iodide. The molecular structures of five complexes, bearing an unreduced form of redox-active ligand, have been established by single-crystal X-ray analysis. The spectral data, electrochemical measurements, and DFT calculations indicate the significant transformations of the molecular orbitals of 1-5 upon complexation with Lewis acids. The reduction potentials of o-(imino)quinones in complexes with metal halides shift into the anodic region versus uncoordinated ones. The choice of metal halide allows varying the shift magnitude up to 1.7 V in 2·CdI2. The change of the oxidizing ability of the 1-5 upon coordination with Lewis acids enables the oxidation of mercury and ferrocene, infeasible for free ligands.
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Ershova I. V. et al. Complexes of Metal Halides with Unreduced o-(Imino)quinones. // Inorganic Chemistry. 2021. Vol. 60. No. 16. pp. 12309-12322.
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Ershova I. V., Meshcheryakova I. N., Trofimova O. Yu., Pashanova K. I., Arsenyeva K. V., Khamaletdinova N. M., Smolyaninov I. V., Arsenyev M. V., Cherkasov A. V., Piskunov A. V. Complexes of Metal Halides with Unreduced o-(Imino)quinones. // Inorganic Chemistry. 2021. Vol. 60. No. 16. pp. 12309-12322.
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TY - JOUR
DO - 10.1021/acs.inorgchem.1c01514
UR - https://doi.org/10.1021/acs.inorgchem.1c01514
TI - Complexes of Metal Halides with Unreduced o-(Imino)quinones.
T2 - Inorganic Chemistry
AU - Ershova, Irina V
AU - Meshcheryakova, Irina N
AU - Trofimova, Olesya Yu
AU - Pashanova, Kira I
AU - Arsenyeva, Kseniya V
AU - Khamaletdinova, N M
AU - Smolyaninov, Ivan V.
AU - Arsenyev, Maxim V
AU - Cherkasov, Anton V
AU - Piskunov, Alexander V.
PY - 2021
DA - 2021/08/02
PB - American Chemical Society (ACS)
SP - 12309-12322
IS - 16
VL - 60
PMID - 34339176
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2021_Ershova,
author = {Irina V Ershova and Irina N Meshcheryakova and Olesya Yu Trofimova and Kira I Pashanova and Kseniya V Arsenyeva and N M Khamaletdinova and Ivan V. Smolyaninov and Maxim V Arsenyev and Anton V Cherkasov and Alexander V. Piskunov},
title = {Complexes of Metal Halides with Unreduced o-(Imino)quinones.},
journal = {Inorganic Chemistry},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.inorgchem.1c01514},
number = {16},
pages = {12309--12322},
doi = {10.1021/acs.inorgchem.1c01514}
}
Cite this
MLA
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Ershova, Irina V., et al. “Complexes of Metal Halides with Unreduced o-(Imino)quinones..” Inorganic Chemistry, vol. 60, no. 16, Aug. 2021, pp. 12309-12322. https://doi.org/10.1021/acs.inorgchem.1c01514.