Inorganic Chemistry, volume 61, issue 12, pages 4879-4886
Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior
Shvanskaya Larisa
1, 2
,
Yakubovich Olga
2
,
Kiriukhina Galina
2, 3
,
Ivanova Anna
4
,
Volkov Anatoly S
2
,
Dimitrova Olga
2
,
Borovikova Elena Yu
2, 5
,
Volkova Olga S
1, 2, 6
,
Vasiliev A. N.
1, 2, 6
Publication type: Journal Article
Publication date: 2022-03-17
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We synthesized single crystals of Na0.55Ni6(OH)3(H0.61PO4)4 (I) and polycrystals of (Na, Ni)0.64Ni5.68(OH)3(H0.67PO4)4 (II) with ellenbergerite-like structures using the hydrothermal method. The phases crystallize in the hexagonal space group P63mc with the following unit cell parameters: a = 12.5342(1) Å, c = 4.9470(1) Å, and V = 673.08(2) Å3 for I; a = 12.4708(2) Å, c = 4.9435(2) Å, and V = 665.82(2) Å3 for II; and Z = 2. Their crystal structures are based on a 3D framework built from NiO6 octahedra and PO4 tetrahedra. The difference between I and II lies in the way the structural channels are filled along the [001] direction. These channels accommodate segments of Na- and (Na, Ni)-centered chains of face-sharing octahedra in the structures I and II, respectively. The magnetic susceptibility χ and the specific heat Cp evidence pronounced low-dimensional magnetic behavior at elevated temperatures and the formation of the weakly ferromagnetic long-range order at TNI = 61 K and TNII = 63 K. Analysis of the χ(T) data within both chain and dimer spin models allows the estimation of the leading exchange interaction parameters in the compounds under study.
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Minerals
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Minerals
1 publication, 25%
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Moscow University Bulletin. Series 4: Geology
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Moscow University Bulletin. Series 4: Geology
1 publication, 25%
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Moscow University Geology Bulletin
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Moscow University Geology Bulletin
1 publication, 25%
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New Journal of Chemistry
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New Journal of Chemistry
1 publication, 25%
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1
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Citations by publishers
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 25%
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Moscow University Press
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Moscow University Press
1 publication, 25%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 25%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 25%
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1
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Shvanskaya L. et al. Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior // Inorganic Chemistry. 2022. Vol. 61. No. 12. pp. 4879-4886.
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Shvanskaya L., Yakubovich O., Krikunova P. V., Kiriukhina G., Ivanova A., Volkov A. S., Dimitrova O., Borovikova E. Yu., Volkova O. S., Vasiliev A. N. Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior // Inorganic Chemistry. 2022. Vol. 61. No. 12. pp. 4879-4886.
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TY - JOUR
DO - 10.1021/acs.inorgchem.1c03597
UR - https://doi.org/10.1021%2Facs.inorgchem.1c03597
TI - Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior
T2 - Inorganic Chemistry
AU - Volkova, Olga S
AU - Borovikova, Elena Yu
AU - Shvanskaya, Larisa
AU - Yakubovich, Olga
AU - Krikunova, Polina V
AU - Kiriukhina, Galina
AU - Ivanova, Anna
AU - Volkov, Anatoly S
AU - Dimitrova, Olga
AU - Vasiliev, A. N.
PY - 2022
DA - 2022/03/17 00:00:00
PB - American Chemical Society (ACS)
SP - 4879-4886
IS - 12
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2022_Shvanskaya,
author = {Olga S Volkova and Elena Yu Borovikova and Larisa Shvanskaya and Olga Yakubovich and Polina V Krikunova and Galina Kiriukhina and Anna Ivanova and Anatoly S Volkov and Olga Dimitrova and A. N. Vasiliev},
title = {Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Facs.inorgchem.1c03597},
number = {12},
pages = {4879--4886},
doi = {10.1021/acs.inorgchem.1c03597}
}
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Shvanskaya, Larisa, et al. “Nonstoichiometric Ellenbergerite-Type Phosphates: Hydrothermal Synthesis, Crystal Chemistry, and Magnetic Behavior.” Inorganic Chemistry, vol. 61, no. 12, Mar. 2022, pp. 4879-4886. https://doi.org/10.1021%2Facs.inorgchem.1c03597.