Inorganic Chemistry, volume 61, issue 24, pages 9012-9018
High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate
Zitong Zhao
1
,
Ran Liu
1
,
LINLIN GUO
1
,
Shuang Liu
1
,
MINGHONG SUI
1
,
Shifeng Niu
1
,
Liu Bo
1
,
Peng Wang
1
,
Zhen Yao
1
,
Bingbing Liu
1
Publication type: Journal Article
Publication date: 2022-06-06
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The pentazolate anion, cyclo-N5-, has received extensive attention as a new generation of energetic species for explosive or propulsion applications. Binary pentazolate compounds have been obtained under high-pressure conditions and their stability enhancement is crucial for obtaining more competitive high energy density materials (HEDMs). Here, we report the synthesis of a new solid phase of lithium pentazolate (space group P21/c) through the chemical transformation of pure lithium azide under high-pressure and high-temperature conditions. Upon decompression, the structural transition from P21/c-LiN5 to P21/m-LiN5 at ∼15.6 GPa was observed for the first time. Cyclo-N5- can be traced down to ∼5.7 GPa at room temperature and recovered to ambient pressure under a low-temperature condition (80 K). Our results reveal the enhancement of pentazolate anion stability with the increasing content of metal cations and demonstrate that low temperature is an effective route for the recovery of the pentazolate anion.
Top-30
Citations by journals
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Journal of Physical Chemistry C
1 publication, 25%
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FirePhysChem
1 publication, 25%
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Inorganic Chemistry
1 publication, 25%
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Russian Chemical Reviews
1 publication, 25%
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Citations by publishers
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2
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American Chemical Society (ACS)
2 publications, 50%
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Elsevier
1 publication, 25%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 25%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Zhao Z. et al. High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate // Inorganic Chemistry. 2022. Vol. 61. No. 24. pp. 9012-9018.
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Zhao Z., Liu R., GUO L., Liu S., SUI M., Niu S., Bo L., Wang P., Yao Z., Liu B. High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate // Inorganic Chemistry. 2022. Vol. 61. No. 24. pp. 9012-9018.
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TY - JOUR
DO - 10.1021/acs.inorgchem.2c00112
UR - https://doi.org/10.1021/acs.inorgchem.2c00112
TI - High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate
T2 - Inorganic Chemistry
AU - Zhao, Zitong
AU - Liu, Ran
AU - GUO, LINLIN
AU - Liu, Shuang
AU - SUI, MINGHONG
AU - Niu, Shifeng
AU - Yao, Zhen
AU - Liu, Bingbing
AU - Bo, Liu
AU - Wang, Peng
PY - 2022
DA - 2022/06/06 00:00:00
PB - American Chemical Society (ACS)
SP - 9012-9018
IS - 24
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2022_Zhao,
author = {Zitong Zhao and Ran Liu and LINLIN GUO and Shuang Liu and MINGHONG SUI and Shifeng Niu and Zhen Yao and Bingbing Liu and Liu Bo and Peng Wang},
title = {High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.inorgchem.2c00112},
number = {24},
pages = {9012--9018},
doi = {10.1021/acs.inorgchem.2c00112}
}
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Zhao, Zitong, et al. “High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate.” Inorganic Chemistry, vol. 61, no. 24, Jun. 2022, pp. 9012-9018. https://doi.org/10.1021/acs.inorgchem.2c00112.