Inorganic Chemistry, volume 61, issue 21, pages 8193-8205

Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis

Publication typeJournal Article
Publication date2022-05-17
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.6
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis, transformation, and application in catalysis of triphenyllead hydroperoxide, the first dioxygen lead complex, are described. Triphenyllead hydroperoxide is characterized by 207Pb nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and single-crystal X-ray diffraction, revealing the first one-dimensional (1D) coordination peroxo polymer. Photolytic isomorphous transformation of Ph3PbOOH yields a mixed hydroxo/superoxo crystalline structure, the first nonalkali superoxo crystalline metal salt, which is stable up to 100 °C. Upon further photolysis, another isomorphous transformation of the superoxide to hydroxide is observed. These are the first single-crystal-to-single-crystal hydroperoxide-to-superoxide and then to hydroxide transformations reported to date. Photolysis of triphenyllead hydroperoxide yields two forms of superoxide-doped crystalline structures that are distinguished by widely different characteristic relaxation times. The use of Ph3PbOOH as an easy-to-handle solid two-electron oxidant for the highly enantioselective epoxidation of olefins is described.

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Medvedev A. G. et al. Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis // Inorganic Chemistry. 2022. Vol. 61. No. 21. pp. 8193-8205.
GOST all authors (up to 50) Copy
Medvedev A. G., Grishanov D. A., Mikhaylov A., Churakov A. V., Tripolskaya T. A., Ottenbacher R. V., Bryliakov K. P., Shames A. I., Lev O., Prikhodchenko P. V. Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis // Inorganic Chemistry. 2022. Vol. 61. No. 21. pp. 8193-8205.
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TY - JOUR
DO - 10.1021/acs.inorgchem.2c00487
UR - https://doi.org/10.1021%2Facs.inorgchem.2c00487
TI - Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis
T2 - Inorganic Chemistry
AU - Tripolskaya, Tatiana A
AU - Medvedev, Alexander G.
AU - Grishanov, Dmitry A
AU - Mikhaylov, Alexey
AU - Churakov, Andrei V.
AU - Ottenbacher, Roman V
AU - Bryliakov, Konstantin P.
AU - Shames, Alexander I.
AU - Lev, Ovadia
AU - Prikhodchenko, Petr V.
PY - 2022
DA - 2022/05/17 00:00:00
PB - American Chemical Society (ACS)
SP - 8193-8205
IS - 21
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
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@article{2022_Medvedev
author = {Tatiana A Tripolskaya and Alexander G. Medvedev and Dmitry A Grishanov and Alexey Mikhaylov and Andrei V. Churakov and Roman V Ottenbacher and Konstantin P. Bryliakov and Alexander I. Shames and Ovadia Lev and Petr V. Prikhodchenko},
title = {Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021%2Facs.inorgchem.2c00487},
number = {21},
pages = {8193--8205},
doi = {10.1021/acs.inorgchem.2c00487}
}
MLA
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MLA Copy
Medvedev, Alexander G., et al. “Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis.” Inorganic Chemistry, vol. 61, no. 21, May. 2022, pp. 8193-8205. https://doi.org/10.1021%2Facs.inorgchem.2c00487.
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