Inorganic Chemistry, volume 61, issue 18, pages 7060-7068
Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3 (VO4 )2 Single Crystals
Kuz’micheva Galina M.
1
,
Ivleva Liudmila I
2
,
Kaurova I. A.
1
,
Khramov Evgeny V
3
,
Rybakov Victor B.
4
,
Fionov Yuri A
5
,
3
4
Publication type: Journal Article
Publication date: 2022-04-26
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The crystal and local structures of Czochralski-grown calcium orthovanadate (Ca3(VO4)2) single crystals doped with over-stoichiometric 0.05 wt % Mn2O3 (CVO:0.05Mn) and annealed under different conditions are studied by single-crystal conventional and synchrotron X-ray diffraction, X-ray absorption spectroscopy, and electron paramagnetic resonance for the first time. Bottom (annealing in air) and top (annealing in air and in vacuum) parts of the CVO:0.05Mn crystal differ in the manganese content (higher in the bottom part), formal charge (Mn4+ and Mn(3+δ)+, respectively), and color (orange bottom part; light orange and yellow top parts annealed in air and vacuum, respectively). Manganese ions are located in one (Ca3, distorted two-capped trigonal prism) of five crystallographic Ca sites and have octahedral coordination, which is consistent with crystal-chemical properties of transition-metal ions. The presence of vacancies in one of three V sites is revealed. Formal charge 5+ for vanadium ions is confirmed by X-ray photoelectron spectroscopy. Different colors of CVO:Mn crystals and different formal charges of manganese are explained depending on the growth and post-growth treatment conditions.
Citations by journals
|
1
|
|
|
Journal of Luminescence
|
Journal of Luminescence
1 publication, 50%
|
|
Solid State Sciences
|
Solid State Sciences
1 publication, 50%
|
|
1
|
Citations by publishers
|
1
2
|
|
|
Elsevier
|
Elsevier
2 publications, 100%
|
|
1
2
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[2],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Luminescence","Solid State Sciences"],"ids":[7075,10336],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier"],"ids":[17],"codes":[0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[2],"backgroundColor":["#3B82F6"],"percentage":[100],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kuz’micheva G. M. et al. Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3(VO4)2Single Crystals // Inorganic Chemistry. 2022. Vol. 61. No. 18. pp. 7060-7068.
GOST all authors (up to 50)
Copy
Kuz’micheva G. M., Ivleva L. I., Kaurova I. A., Khramov E. V., Lazarenko V. A., Rybakov V. B., Fionov Y. A., Fionov A. S. Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3(VO4)2Single Crystals // Inorganic Chemistry. 2022. Vol. 61. No. 18. pp. 7060-7068.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.2c00503
UR - https://doi.org/10.1021%2Facs.inorgchem.2c00503
TI - Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3(VO4)2Single Crystals
T2 - Inorganic Chemistry
AU - Ivleva, Liudmila I
AU - Khramov, Evgeny V
AU - Lazarenko, Vladimir A
AU - Rybakov, Victor B.
AU - Kuz’micheva, Galina M.
AU - Fionov, Yuri A
AU - Kaurova, I. A.
AU - Fionov, Alexander Sergeevich
PY - 2022
DA - 2022/04/26 00:00:00
PB - American Chemical Society (ACS)
SP - 7060-7068
IS - 18
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex
Copy
@article{2022_Kuz’micheva,
author = {Liudmila I Ivleva and Evgeny V Khramov and Vladimir A Lazarenko and Victor B. Rybakov and Galina M. Kuz’micheva and Yuri A Fionov and I. A. Kaurova and Alexander Sergeevich Fionov},
title = {Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3(VO4)2Single Crystals},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.inorgchem.2c00503},
number = {18},
pages = {7060--7068},
doi = {10.1021/acs.inorgchem.2c00503}
}
Cite this
MLA
Copy
Kuz’micheva, Galina M., et al. “Annealing-Induced Structural Behavior of Mn Dopant Ions in Calcium Orthovanadate Ca3(VO4)2Single Crystals.” Inorganic Chemistry, vol. 61, no. 18, Apr. 2022, pp. 7060-7068. https://doi.org/10.1021%2Facs.inorgchem.2c00503.