volume 62 issue 13 pages 5105-5113

Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization

Publication typeJournal Article
Publication date2023-03-18
scimago Q1
wos Q1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The introduction of a secondary interaction is an efficient strategy to modulate transition-metal-catalyzed ethylene (co)polymerization. In this contribution, O-donor groups were suspended on amine-imine ligands to synthesize a series of nickel complexes. By adjusting the interaction between the nickel metal center and the O-donor group on the ligands, these nickel complexes exhibited high activities for ethylene polymerization (up to 3.48 × 106 gPE·molNi-1·h-1) with high molecular weight up to 5.59 × 105 g·mol-1 and produced good polyethylene elastomers (strain recovery (SR) = 69-81%). In addition, these nickel complexes can catalyze the copolymerization of ethylene with vinyl acetic acid, 6-chloro-1-hexene, 10-undecylenic, 10-undecenoic acid, and 10-undecylenic alcohol to prepare the functionalized polyolefins.
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GOST Copy
Yan-Bing W. et al. Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization // Inorganic Chemistry. 2023. Vol. 62. No. 13. pp. 5105-5113.
GOST all authors (up to 50) Copy
Yan-Bing W., Wang Y., Nan C., Zhuo W., Zou C., Jiang H., Hao X., Chen C., Song M. Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization // Inorganic Chemistry. 2023. Vol. 62. No. 13. pp. 5105-5113.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.2c04240
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c04240
TI - Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization
T2 - Inorganic Chemistry
AU - Yan-Bing, Wang
AU - Wang, Yanbing
AU - Nan, Chenlong
AU - Zhuo, Weize
AU - Zou, Chen
AU - Jiang, Hui
AU - Hao, Xinqi
AU - Chen, Changle
AU - Song, Maoping
PY - 2023
DA - 2023/03/18
PB - American Chemical Society (ACS)
SP - 5105-5113
IS - 13
VL - 62
PMID - 36933227
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Yan-Bing,
author = {Wang Yan-Bing and Yanbing Wang and Chenlong Nan and Weize Zhuo and Chen Zou and Hui Jiang and Xinqi Hao and Changle Chen and Maoping Song},
title = {Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization},
journal = {Inorganic Chemistry},
year = {2023},
volume = {62},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c04240},
number = {13},
pages = {5105--5113},
doi = {10.1021/acs.inorgchem.2c04240}
}
MLA
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MLA Copy
Yan-Bing, Wang, et al. “Amine–Imine Nickel Catalysts with Pendant O-Donor Groups for Ethylene (Co)Polymerization.” Inorganic Chemistry, vol. 62, no. 13, Mar. 2023, pp. 5105-5113. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c04240.