Inorganic Chemistry, volume 54, issue 7, pages 3600-3607
Highly Conductive Li Garnets by a Multielement Doping Strategy
1
Department
of Chemistry, University of Calgary, 2500 University Dr. NW, Calgary, Alberta T2N 1N4, Canada
|
Publication type: Journal Article
Publication date: 2015-03-20
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Highly conductive Li7La3Zr2O12 (LLZ) garnet-type solid electrolytes were further optimized to improve Li-ion conduction by La(3+)-sites substitution with Ba(2+) and Zr(4+)-sites substitution with Ta(5+) and Nb(5+). Garnet-structured metal oxides of the nominal chemical compositions Li6.65La2.75Ba0.25Zr1.4Ta0.5Nb0.1O12, Li6.4La3Zr1.4Ta0.6-xNbxO12 (x = 0, 0.1, 0.2, and 0.3), and the parent LLZ, as a reference, were prepared via conventional solid-state reaction to investigate the effect of multielement doping on ionic conductivity. The phase formation, morphology, and Li ion conductivity were characterized using powder X-ray diffraction (PXRD), scanning electron microscopy, and alternating current impedance spectroscopy methods, respectively. In addition, solid-state (27)Al and (7)Li magic-angle spinning (MAS) NMR was used to study the effect of "Al doping" on the investigated multielement doped Li-stuffed garnet metal oxides. All the prepared samples obtained the cubic garnet-type structure (space group: Ia3̅d; No. 230) at 1150 °C, similar to that of cubic LLZ. Except for Li6.4La3Zr1.4Ta0.6O12, all the members show Al content by Al MAS NMR. However, it was not possible to detect Al-based impurity phases using PXRD in any of the investigated garnets. Among the samples investigated in this work, "Al-free" Li6.4La3Zr1.4Ta0.6O12 demonstrated a bulk Li ion conductivity of 0.72 mS cm(-1) at 25 °C, with apparent activation energy of 0.26 eV, significantly higher than the parent LLZ.
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- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Tong X., Thangadurai V., Wachsman E. D. Highly Conductive Li Garnets by a Multielement Doping Strategy // Inorganic Chemistry. 2015. Vol. 54. No. 7. pp. 3600-3607.
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Tong X., Thangadurai V., Wachsman E. D. Highly Conductive Li Garnets by a Multielement Doping Strategy // Inorganic Chemistry. 2015. Vol. 54. No. 7. pp. 3600-3607.
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TY - JOUR
DO - 10.1021/acs.inorgchem.5b00184
UR - https://doi.org/10.1021/acs.inorgchem.5b00184
TI - Highly Conductive Li Garnets by a Multielement Doping Strategy
T2 - Inorganic Chemistry
AU - Tong, Xia
AU - Thangadurai, Venkataraman
AU - Wachsman, Eric D.
PY - 2015
DA - 2015/03/20 00:00:00
PB - American Chemical Society (ACS)
SP - 3600-3607
IS - 7
VL - 54
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2015_Tong,
author = {Xia Tong and Venkataraman Thangadurai and Eric D. Wachsman},
title = {Highly Conductive Li Garnets by a Multielement Doping Strategy},
journal = {Inorganic Chemistry},
year = {2015},
volume = {54},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.inorgchem.5b00184},
number = {7},
pages = {3600--3607},
doi = {10.1021/acs.inorgchem.5b00184}
}
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Tong, Xia, et al. “Highly Conductive Li Garnets by a Multielement Doping Strategy.” Inorganic Chemistry, vol. 54, no. 7, Mar. 2015, pp. 3600-3607. https://doi.org/10.1021/acs.inorgchem.5b00184.