volume 55 issue 15 pages 7323-7325

Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction

Publication typeJournal Article
Publication date2016-07-19
scimago Q1
wos Q1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A chiral C3-symmetric cubane cluster, [Cu4I4(TMP)4], with enough long Cu-Cu distances to eliminate the presence of Cu-Cu interaction has been synthesized and characterized, which shows simultaneous luminescent thermochromism, solvatochromism, vapochromism, and mechanochromism and is a multiply stimuli-responsive chromic luminescent material. This complex could partly transform into a yellow-emissive bicapped cubane cluster, [Cu6I6(TMP)4(MeCN)2], in acetonitrile (MeCN) vapor and solution, which provides some insight into vapochromism and solvatiochromism. This work challenges and makes us reconsider the conventional viewpoint that Cu-Cu interaction is involved in thermochromism and mechanochromism of copper complexes.
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GOST Copy
Yang K. et al. Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction // Inorganic Chemistry. 2016. Vol. 55. No. 15. pp. 7323-7325.
GOST all authors (up to 50) Copy
Yang K., Li S. L., Zhang F., Zhang X. Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction // Inorganic Chemistry. 2016. Vol. 55. No. 15. pp. 7323-7325.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.6b00922
UR - https://doi.org/10.1021/acs.inorgchem.6b00922
TI - Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction
T2 - Inorganic Chemistry
AU - Yang, Kai
AU - Li, Shi Li
AU - Zhang, Fu-Qiang
AU - Zhang, Xianming
PY - 2016
DA - 2016/07/19
PB - American Chemical Society (ACS)
SP - 7323-7325
IS - 15
VL - 55
PMID - 27433878
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Yang,
author = {Kai Yang and Shi Li Li and Fu-Qiang Zhang and Xianming Zhang},
title = {Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction},
journal = {Inorganic Chemistry},
year = {2016},
volume = {55},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.inorgchem.6b00922},
number = {15},
pages = {7323--7325},
doi = {10.1021/acs.inorgchem.6b00922}
}
MLA
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MLA Copy
Yang, Kai, et al. “Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction.” Inorganic Chemistry, vol. 55, no. 15, Jul. 2016, pp. 7323-7325. https://doi.org/10.1021/acs.inorgchem.6b00922.