Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies
2
Department
of Physics, Knox College, Galesburg, Illinois 61401, United States
|
Publication type: Journal Article
Publication date: 2016-09-22
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
27676612
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and characterization of several electron-poor iron(II) porphyrin (FeTFPPBr8) complexes with axial imidazole ligands are reported. The single-crystal X-ray structures have been studied by a combination of crystal packing and Hirshfeld surface calculations, which explained the unusual axial-ligand geometries, e.g., the strong tilt of the Fe-NIm bonds and the imidazole planes. The six-coordinate [Fe(TFPPBr8)(1-MeIm)2] was studied by multiple-temperature solid-state Mössbauer spectroscopy, which suggested that it is a low-spin complex with δ ∼ 0.32-0.38 mm/s and ΔEQ ∼ 1.0 mm/s.
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14
Total citations:
14
Citations from 2025:
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(14.29%)
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Hu B. et al. Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies // Inorganic Chemistry. 2016. Vol. 55. No. 19. pp. 9632-9643.
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Hu B., He M., Yao Z., Schulz C. E., Li J. Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies // Inorganic Chemistry. 2016. Vol. 55. No. 19. pp. 9632-9643.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.6b01364
UR - https://doi.org/10.1021/acs.inorgchem.6b01364
TI - Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies
T2 - Inorganic Chemistry
AU - Hu, Bin
AU - He, Mingrui
AU - Yao, Zhen
AU - Schulz, Charles E.
AU - Li, Jian-Feng
PY - 2016
DA - 2016/09/22
PB - American Chemical Society (ACS)
SP - 9632-9643
IS - 19
VL - 55
PMID - 27676612
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Hu,
author = {Bin Hu and Mingrui He and Zhen Yao and Charles E. Schulz and Jian-Feng Li},
title = {Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies},
journal = {Inorganic Chemistry},
year = {2016},
volume = {55},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.inorgchem.6b01364},
number = {19},
pages = {9632--9643},
doi = {10.1021/acs.inorgchem.6b01364}
}
Cite this
MLA
Copy
Hu, Bin, et al. “Unique Axial Imidazole Geometries of Fully Halogenated Iron(II) Porphyrin Complexes: Crystal Structures and Mössbauer Spectroscopic Studies.” Inorganic Chemistry, vol. 55, no. 19, Sep. 2016, pp. 9632-9643. https://doi.org/10.1021/acs.inorgchem.6b01364.