Inorganic Chemistry

, том 56 , издание 2 , страницы 974-983

Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.

Francis A Leblanc ¹

Andreas Decken ¹

T. Stanley Cameron ²

Jack Passmore ¹

J. Rautiainen ³

Thomas K. Whidden ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

Department of Chemistry, University Of New Brunswick, Fredericton, New Brunswick E3B 5A3, Canada |

Department of Chemistry, Dalhousie University, P.O. Box 15000, Halifax, Nova Scotia B3H 4R2, Canada |

Department of Chemistry and Nanoscience Center, University of Jyväskylä, P.O. Box 35, Jyväskylä FI-40014, Finland |

Тип публикации: Journal Article

Дата публикации: 2017-01-03

American Chemical Society (ACS)

Inorganic Chemistry

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CiteScore: 7.4

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ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.6b02670

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PubMed ID: 28045506

Inorganic Chemistry

Physical and Theoretical Chemistry

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A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]- was compared with that of some related known weakly coordinating anions by appropriate DFT calculations.

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Leblanc F. A. et al. Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. // Inorganic Chemistry. 2017. Vol. 56. No. 2. pp. 974-983.

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Leblanc F. A., Decken A., Cameron T. S., Passmore J., Rautiainen J., Whidden T. K. Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. // Inorganic Chemistry. 2017. Vol. 56. No. 2. pp. 974-983.

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TY - JOUR

DO - 10.1021/acs.inorgchem.6b02670

UR - https://doi.org/10.1021/acs.inorgchem.6b02670

TI - Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.

T2 - Inorganic Chemistry

AU - Leblanc, Francis A

AU - Decken, Andreas

AU - Cameron, T. Stanley

AU - Passmore, Jack

AU - Rautiainen, J.

AU - Whidden, Thomas K.

PY - 2017

DA - 2017/01/03

PB - American Chemical Society (ACS)

SP - 974-983

IS - 2

VL - 56

PMID - 28045506

SN - 0020-1669

SN - 1520-510X

ER -

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@article{2017_Leblanc,

author = {Francis A Leblanc and Andreas Decken and T. Stanley Cameron and Jack Passmore and J. Rautiainen and Thomas K. Whidden},

title = {Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.},

journal = {Inorganic Chemistry},

year = {2017},

volume = {56},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/acs.inorgchem.6b02670},

number = {2},

pages = {974--983},

doi = {10.1021/acs.inorgchem.6b02670}

}

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Leblanc, Francis A., et al. “Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane..” Inorganic Chemistry, vol. 56, no. 2, Jan. 2017, pp. 974-983. https://doi.org/10.1021/acs.inorgchem.6b02670.