American Chemical Society (ACS)
Inorganic Chemistry
,  volume 56 ,  issue 2 ,  pages 974-983

Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.

Publication type: Journal Article
Publication date: 2017-01-03
American Chemical Society (ACS)
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]- was compared with that of some related known weakly coordinating anions by appropriate DFT calculations.
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GOST Copy
Leblanc F. A. et al. Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. // Inorganic Chemistry. 2017. Vol. 56. No. 2. pp. 974-983.
GOST all authors (up to 50) Copy
Leblanc F. A., Decken A., Cameron T. S., Passmore J., Rautiainen J., Whidden T. K. Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. // Inorganic Chemistry. 2017. Vol. 56. No. 2. pp. 974-983.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.6b02670
UR - https://doi.org/10.1021/acs.inorgchem.6b02670
TI - Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.
T2 - Inorganic Chemistry
AU - Leblanc, Francis A
AU - Decken, Andreas
AU - Cameron, T. Stanley
AU - Passmore, Jack
AU - Rautiainen, J.
AU - Whidden, Thomas K.
PY - 2017
DA - 2017/01/03
PB - American Chemical Society (ACS)
SP - 974-983
IS - 2
VL - 56
PMID - 28045506
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Leblanc,
author = {Francis A Leblanc and Andreas Decken and T. Stanley Cameron and Jack Passmore and J. Rautiainen and Thomas K. Whidden},
title = {Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane.},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.inorgchem.6b02670},
number = {2},
pages = {974--983},
doi = {10.1021/acs.inorgchem.6b02670}
}
MLA
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MLA Copy
Leblanc, Francis A., et al. “Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane..” Inorganic Chemistry, vol. 56, no. 2, Jan. 2017, pp. 974-983. https://doi.org/10.1021/acs.inorgchem.6b02670.