New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives
Publication type: Journal Article
Publication date: 2017-04-17
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28414221
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Fullerene C98 possesses 259 isomers obeying the isolated pentagon rule (IPR), from which two, nos. 116 and 248, have been confirmed earlier as chloro derivatives. High-temperature chlorination of C98-containing mixtures afforded crystals of several chloro derivatives, and their structure elucidation by X-ray crystallography revealed the presence of new isomers, nos. 107, 109, and 120, in the fullerene soot. Evidence for an isomer of no. 111 is also presented. In addition, a new chloride of the known isomer 248 has been isolated and structurally studied. The chlorination patterns of the chlorides are discussed in terms of the formation of isolated C═C bonds and aromatic substructures on the fullerene cages.
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Total citations:
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Citations from 2024:
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Jin F., Yang S., Troyanov S. New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives // Inorganic Chemistry. 2017. Vol. 56. No. 9. pp. 4780-4783.
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Jin F., Yang S., Troyanov S. New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives // Inorganic Chemistry. 2017. Vol. 56. No. 9. pp. 4780-4783.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b00568
UR - https://doi.org/10.1021/acs.inorgchem.7b00568
TI - New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives
T2 - Inorganic Chemistry
AU - Jin, Fei
AU - Yang, Shangfeng
AU - Troyanov, Sergey
PY - 2017
DA - 2017/04/17
PB - American Chemical Society (ACS)
SP - 4780-4783
IS - 9
VL - 56
PMID - 28414221
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2017_Jin,
author = {Fei Jin and Shangfeng Yang and Sergey Troyanov},
title = {New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.inorgchem.7b00568},
number = {9},
pages = {4780--4783},
doi = {10.1021/acs.inorgchem.7b00568}
}
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MLA
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Jin, Fei, et al. “New Isolated-Pentagon-Rule Isomers of Fullerene C98 Captured as Chloro Derivatives.” Inorganic Chemistry, vol. 56, no. 9, Apr. 2017, pp. 4780-4783. https://doi.org/10.1021/acs.inorgchem.7b00568.
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