Inorganic Chemistry, volume 56, issue 11, pages 6681-6687
Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.
Publication type: Journal Article
Publication date: 2017-05-09
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Inspired by the ongoing search for new superionic lithium thiophosphates for use in solid-state batteries, we present the synthesis and structural characterization of Li2P2S6, a novel crystalline lithium thiophosphate. Whereas M2P2S6 with the different alkaline elements (M = Na, K, Rb, Cs) is known, the lithium counterpart has not been reported yet. Herein, we present a combination of synchrotron pair distribution function analysis and neutron powder diffraction to elucidate the crystal structure and possible Li+ diffusion pathways of Li2P2S6. Additionally, impedance spectroscopy is used to evaluate its ionic conductivity. We show that Li2P2S6 possesses P2S62- polyhedral units with edge-sharing PS4 tetrahedra and only one-dimensional diffusion pathways with localized Li-Li pairs, leading to a low ionic conductivity for lithium.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Dietrich C. et al. Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6. // Inorganic Chemistry. 2017. Vol. 56. No. 11. pp. 6681-6687.
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Dietrich C., Weber D. A., Culver S. P., Senyshyn A., Sedlmaier S. J., Indris S., Janek J., Zeier W. G. Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6. // Inorganic Chemistry. 2017. Vol. 56. No. 11. pp. 6681-6687.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b00751
UR - https://doi.org/10.1021/acs.inorgchem.7b00751
TI - Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.
T2 - Inorganic Chemistry
AU - Dietrich, Christian
AU - Sedlmaier, Stefan J.
AU - Indris, Sylvio
AU - Zeier, Wolfgang G.
AU - Weber, Dominik A.
AU - Culver, Sean P
AU - Senyshyn, A.
AU - Janek, Jürgen
PY - 2017
DA - 2017/05/09 00:00:00
PB - American Chemical Society (ACS)
SP - 6681-6687
IS - 11
VL - 56
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Dietrich,
author = {Christian Dietrich and Stefan J. Sedlmaier and Sylvio Indris and Wolfgang G. Zeier and Dominik A. Weber and Sean P Culver and A. Senyshyn and Jürgen Janek},
title = {Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.inorgchem.7b00751},
number = {11},
pages = {6681--6687},
doi = {10.1021/acs.inorgchem.7b00751}
}
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Dietrich, Christian, et al. “Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6..” Inorganic Chemistry, vol. 56, no. 11, May. 2017, pp. 6681-6687. https://doi.org/10.1021/acs.inorgchem.7b00751.