Gallium Hydrides with a Radical-Anionic Ligand
Publication type: Journal Article
Publication date: 2017-10-12
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29023115
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Cl2GaH with a sodium salt of the dpp-Bian radical-anion (dpp-Bian•-)Na (dpp-Bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) affords paramagnetic gallane (dpp-Bian•-)Ga(Cl)H (1). Oxidation of (dpp-Bian2-)Ga-Ga(dpp-Bian2-) (2) with N2O results in the dimeric oxide (dpp-Bian•-)Ga(μ2-O)2Ga(dpp-Bian•-) (3). A treatment of the oxide 3 with phenylsilane affords paramagnetic gallium hydrides (dpp-Bian•-)GaH2 (4) and (dpp-Bian•-)Ga{OSi(Ph)H2}H (5) depending on the reagent's stoichiometry. The reaction of digallane 2 with benzaldehyde produces pinacolate (dpp-Bian•-)Ga(O2C2H2Ph2) (6). In the presence of PhSiH3, the reaction between digallane 2 and benzaldehyde (2: PhSiH3: PhC(H)O = 1:4:4) affords compound 4. The newly prepared complexes 1, 3-6 consist of a spin-labeled diimine ligand-dpp-Bian radical-anion. The presence of the ligand-localized unpaired electron allows the use of the ESR spectroscopy for characterization of the gallium hydrides reported. The molecular structures of compounds 1, 3-6 have been determined by the single-crystal X-ray analysis.
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Sokolov V. G. et al. Gallium Hydrides with a Radical-Anionic Ligand // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 13401-13410.
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Sokolov V. G., Koptseva T. S., Moskalev M. V., Bazyakina N. L., Piskunov A. V., Cherkasov A. V., Fedushkin I. L. Gallium Hydrides with a Radical-Anionic Ligand // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 13401-13410.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02138
UR - https://doi.org/10.1021/acs.inorgchem.7b02138
TI - Gallium Hydrides with a Radical-Anionic Ligand
T2 - Inorganic Chemistry
AU - Sokolov, Vladimir G
AU - Koptseva, Tatyana S
AU - Moskalev, Mikhail V
AU - Bazyakina, Natalia L
AU - Piskunov, Alexander V.
AU - Cherkasov, Anton V
AU - Fedushkin, I. L.
PY - 2017
DA - 2017/10/12
PB - American Chemical Society (ACS)
SP - 13401-13410
IS - 21
VL - 56
PMID - 29023115
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Sokolov,
author = {Vladimir G Sokolov and Tatyana S Koptseva and Mikhail V Moskalev and Natalia L Bazyakina and Alexander V. Piskunov and Anton V Cherkasov and I. L. Fedushkin},
title = {Gallium Hydrides with a Radical-Anionic Ligand},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.7b02138},
number = {21},
pages = {13401--13410},
doi = {10.1021/acs.inorgchem.7b02138}
}
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Sokolov, Vladimir G., et al. “Gallium Hydrides with a Radical-Anionic Ligand.” Inorganic Chemistry, vol. 56, no. 21, Oct. 2017, pp. 13401-13410. https://doi.org/10.1021/acs.inorgchem.7b02138.