Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells
Тип публикации: Journal Article
Дата публикации: 2017-10-11
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SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29019665
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Three new tris-heteroleptic complexes of ruthenium(II) were designed by coordinating the metal center with cyclometalating, anchoring, and auxiliary ligands with different donor substituents. N-Hexylcarbazole, N-hexylphenothiazine, and N-hexyldiphenylamine donor moieties were used as substituents on the auxiliary ligands for SA633, SA634, and SA635, respectively. Complexes were characterized by 1H and 13C 2D-COSY NMR techniques. These complexes provide power conversion efficiencies in the range of 7.6-8.2% when they are employed in state of the art dye-sensitized solar cells (DSCs) with cobalt electrolyte. Various electrochemical and transient techniques were used to unveil the unexpected differences in the performance of these very similar sensitizers.
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Aghazada S. et al. Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 13437-13445.
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Aghazada S., Ren Y., Wang P., Nazeeruddin M. Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 13437-13445.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02164
UR - https://doi.org/10.1021/acs.inorgchem.7b02164
TI - Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells
T2 - Inorganic Chemistry
AU - Aghazada, Sadig
AU - Ren, Yameng
AU - Wang, Peng
AU - Nazeeruddin, M.
PY - 2017
DA - 2017/10/11
PB - American Chemical Society (ACS)
SP - 13437-13445
IS - 21
VL - 56
PMID - 29019665
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Aghazada,
author = {Sadig Aghazada and Yameng Ren and Peng Wang and M. Nazeeruddin},
title = {Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.7b02164},
number = {21},
pages = {13437--13445},
doi = {10.1021/acs.inorgchem.7b02164}
}
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MLA
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Aghazada, Sadig, et al. “Effect of Donor Groups on the Performance of Cyclometalated Ruthenium Sensitizers in Dye-Sensitized Solar Cells.” Inorganic Chemistry, vol. 56, no. 21, Oct. 2017, pp. 13437-13445. https://doi.org/10.1021/acs.inorgchem.7b02164.
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