An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes
Publication type: Journal Article
Publication date: 2017-11-27
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29172466
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We introduce a new unsymmetric ligand, PDIpCy (PDI = pyridyldiimine; Cy = cyclam), that offers two distinct, noncoupled coordination sites. A series of homo- and heterobimetallic complexes, [Zn2(PDIpCy)(THF)(OTf)4] (1; THF = tetrahydrofuran and OTf = triflate), [Ni2(PDIpCy)(THF)(OTf)2](OTf)2 (2), and [NiZn(PDIpCy)(THF)(OTf)4] (3), are described. The one-electron-reduced compounds, [Zn2(PDIpCy)(OTF)3] (4), [Ni2(PDIpCy)(OTf)](OTf)2 (5), and [NiZn(PDIpCy)(OTf)3] (6), were isolated, and their electronic structures were characterized. The reduced compounds are charge-separated species, with electron storage at either the PDI ligand (4) or at the PDI-bound metal ion (5 and 6).
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12
Total citations:
12
Citations from 2025:
2
(16.67%)
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Haas R. M. et al. An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 14738-14742.
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Haas R. M., Hern Z., Sproules S., Hess C. R. An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 14738-14742.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02294
UR - https://doi.org/10.1021/acs.inorgchem.7b02294
TI - An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes
T2 - Inorganic Chemistry
AU - Haas, Ruth M
AU - Hern, Zachary
AU - Sproules, Stephen
AU - Hess, Corinna R
PY - 2017
DA - 2017/11/27
PB - American Chemical Society (ACS)
SP - 14738-14742
IS - 24
VL - 56
PMID - 29172466
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2017_Haas,
author = {Ruth M Haas and Zachary Hern and Stephen Sproules and Corinna R Hess},
title = {An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.inorgchem.7b02294},
number = {24},
pages = {14738--14742},
doi = {10.1021/acs.inorgchem.7b02294}
}
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MLA
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Haas, Ruth M., et al. “An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes.” Inorganic Chemistry, vol. 56, no. 24, Nov. 2017, pp. 14738-14742. https://doi.org/10.1021/acs.inorgchem.7b02294.
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