Inorganic Chemistry, volume 57, issue 4, pages 1796-1805
Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation
Wang Jiawei
1
,
Niu Yanjun
1
,
Zhang Meng
1
,
Ma Pengtao
1
,
Zhang Chao
1
,
Niu Jingyang
1
,
Wang Jingping
1
1
Henan Key Laboratory
of Polyoxometalate, Institute of Molecular and Crystal Engineering,
College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, People’s Republic of China
|
Publication type: Journal Article
Publication date: 2018-02-07
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A novel class of organophosphonate-based polyoxomolybdate derivatives, K4H5[Ln3(H2O)14{(Mo8O24)(O3PCH2COO)3}2]·23H2O (Ln = Gd (1Gd), Tb (2Tb), Dy (3Dy)), have been fully investigated by a few characterization methods such as single-crystal X-ray crystallography, XRPD, elemental analysis, TGA, and IR spectra. The magnetic properties of 1Gd, 2Tb, and 3Dy were investigated, as well as the solid-state luminescence properties of 2Tb and 3Dy. The catalysis properties of 1Gd, 2Tb, and 3Dy for thioether oxidization have been investigated using hydrogen peroxide (H2O2) as an oxidant. The catalysis study demonstrated the efficient and selective conversion of various thioethers to their corresponding sulfones in excellent yields.
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Citations by publishers
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American Chemical Society (ACS)
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1 publication, 2.44%
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Springer Nature
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Springer Nature
1 publication, 2.44%
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Wiley
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Wiley
1 publication, 2.44%
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Nonferrous Metals Society of China
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Nonferrous Metals Society of China, 1, 2.44%
Nonferrous Metals Society of China
1 publication, 2.44%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Wang J. et al. Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation // Inorganic Chemistry. 2018. Vol. 57. No. 4. pp. 1796-1805.
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Wang J., Niu Y., Zhang M., Ma P., Zhang C., Niu J., Wang J. Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation // Inorganic Chemistry. 2018. Vol. 57. No. 4. pp. 1796-1805.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02672
UR - https://doi.org/10.1021%2Facs.inorgchem.7b02672
TI - Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation
T2 - Inorganic Chemistry
AU - Ma, Pengtao
AU - Wang, Jingping
AU - Niu, Yanjun
AU - Zhang, Chao
AU - Niu, Jingyang
AU - Wang, Jiawei
AU - Zhang, Meng
PY - 2018
DA - 2018/02/07 00:00:00
PB - American Chemical Society (ACS)
SP - 1796-1805
IS - 4
VL - 57
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2018_Wang,
author = {Pengtao Ma and Jingping Wang and Yanjun Niu and Chao Zhang and Jingyang Niu and Jiawei Wang and Meng Zhang},
title = {Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021%2Facs.inorgchem.7b02672},
number = {4},
pages = {1796--1805},
doi = {10.1021/acs.inorgchem.7b02672}
}
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MLA
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Wang, Jiawei, et al. “Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation.” Inorganic Chemistry, vol. 57, no. 4, Feb. 2018, pp. 1796-1805. https://doi.org/10.1021%2Facs.inorgchem.7b02672.
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