Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation
Jiawei Wang
1
,
Yanjun Niu
1
,
Meng Zhang
1
,
Pengtao Ma
1
,
Chao Zhang
1
,
Jingyang Niu
1
,
Jingping Wang
1
Publication type: Journal Article
Publication date: 2018-02-07
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29412645
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A novel class of organophosphonate-based polyoxomolybdate derivatives, K4H5[Ln3(H2O)14{(Mo8O24)(O3PCH2COO)3}2]·23H2O (Ln = Gd (1Gd), Tb (2Tb), Dy (3Dy)), have been fully investigated by a few characterization methods such as single-crystal X-ray crystallography, XRPD, elemental analysis, TGA, and IR spectra. The magnetic properties of 1Gd, 2Tb, and 3Dy were investigated, as well as the solid-state luminescence properties of 2Tb and 3Dy. The catalysis properties of 1Gd, 2Tb, and 3Dy for thioether oxidization have been investigated using hydrogen peroxide (H2O2) as an oxidant. The catalysis study demonstrated the efficient and selective conversion of various thioethers to their corresponding sulfones in excellent yields.
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48
Total citations:
48
Citations from 2024:
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(14%)
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GOST
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Wang J. et al. Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation // Inorganic Chemistry. 2018. Vol. 57. No. 4. pp. 1796-1805.
GOST all authors (up to 50)
Copy
Wang J., Niu Y., Zhang M., Ma P., Zhang C., Niu J., Wang J. Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation // Inorganic Chemistry. 2018. Vol. 57. No. 4. pp. 1796-1805.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02672
UR - https://doi.org/10.1021/acs.inorgchem.7b02672
TI - Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation
T2 - Inorganic Chemistry
AU - Wang, Jiawei
AU - Niu, Yanjun
AU - Zhang, Meng
AU - Ma, Pengtao
AU - Zhang, Chao
AU - Niu, Jingyang
AU - Wang, Jingping
PY - 2018
DA - 2018/02/07
PB - American Chemical Society (ACS)
SP - 1796-1805
IS - 4
VL - 57
PMID - 29412645
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Wang,
author = {Jiawei Wang and Yanjun Niu and Meng Zhang and Pengtao Ma and Chao Zhang and Jingyang Niu and Jingping Wang},
title = {Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.inorgchem.7b02672},
number = {4},
pages = {1796--1805},
doi = {10.1021/acs.inorgchem.7b02672}
}
Cite this
MLA
Copy
Wang, Jiawei, et al. “Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation.” Inorganic Chemistry, vol. 57, no. 4, Feb. 2018, pp. 1796-1805. https://doi.org/10.1021/acs.inorgchem.7b02672.
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