Inorganic Chemistry

, volume 57 , issue 3 , pages 930-934

Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies.

Alexander Tskhovrebov ^{1, 2}

Anna V. Vasileva ¹

Richard H. Goddard ²

Tina Riedel ³

Paul J Dyson ³

V N Mikhaylov ¹

Tatyana V. Serebryanskaya ⁴

V. N. Sorokoumov ¹

Matti Haukka ⁵

Hide authors affiliations Show authors affiliations: 5 affiliations

St. Petersburg State University, Universitetskaya Nab. 7/9, St. Petersburg, Russian Federation |

Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim/Ruhr, Germany |

Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland |

⁴

Research Institute for Physical Chemical Problems of the Belarusian State University, 14, Leningradskaya Str., 220030 Minsk, Belarus |

⁵

Department of Chemistry, University of Jyväskylä, P.O. BOX 35, FI-40014 Jyväskylä, Finland |

Publication type: Journal Article

Publication date: 2018-01-22

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.8b00072

Copy DOI

PubMed ID: 29356518

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO2 results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.

Found

16 citations

Novikov Alexander

🥼 🤝

PhD in Chemistry

411 publications, 8 100 citations, 251 reviews

h-index: 53

Saint Petersburg State University

Lomonosov Moscow State University

National Research University Higher School of Economics

Peoples' Friendship University of Russia

Research interests

Computational chemistry

Machine learning

Non-covalent Interactions

Quantum Chemistry

Reaction mechanisms

Supramolecular chemistry

10 citations

Khrustalev Victor

DSc in Chemistry, professor, professor of the Russian Academy of Sciences

324 publications, 4 021 citations, 4 reviews

h-index: 30

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

8 citations

Kubasov Alexey

🥼 🤝

PhD in Chemistry

114 publications, 1 112 citations, 42 reviews

h-index: 19

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Borides

Coordination Chemistry

Structural chemistry

4 citations

Artemev Alexey

15 publications, 231 citations

h-index: 9

Peoples' Friendship University of Russia

Research interests

Non-covalent Interactions

2 citations

Mikhaylov Vladimir

PhD in Chemistry

20 publications, 380 citations

h-index: 11

Saint Petersburg State University

Research interests

Catalysis

2 citations

Sorokoumov Viktor

PhD in Chemistry

58 publications, 780 citations

h-index: 15

Saint Petersburg State University

I. M. Sechenov Institute of Evolutionary Physiology and Biochemistry of the Russian Academy of Sciences

1 citation

Dorovatovskii Pavel

340 publications, 3 973 citations

h-index: 28

National Research Centre "Kurchatov Institute"

1 citation

Zhukova Anna

🥼 🤝

PhD in Chemistry, associate professor

56 publications, 301 citations, 11 reviews

h-index: 10

Peoples' Friendship University of Russia

Research interests

Heterogeneous catalysis

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GOST |

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GOST Copy

Tskhovrebov A. et al. Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies. // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 930-934.

GOST all authors (up to 50) Copy

Tskhovrebov A., Vasileva A. V., Goddard R. H., Riedel T., Dyson P. J., Mikhaylov V. N., Serebryanskaya T. V., Sorokoumov V. N., Haukka M. Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies. // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 930-934.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acs.inorgchem.8b00072

UR - https://doi.org/10.1021/acs.inorgchem.8b00072

TI - Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies.

T2 - Inorganic Chemistry

AU - Tskhovrebov, Alexander

AU - Vasileva, Anna V.

AU - Goddard, Richard H.

AU - Riedel, Tina

AU - Dyson, Paul J

AU - Mikhaylov, V N

AU - Serebryanskaya, Tatyana V.

AU - Sorokoumov, V. N.

AU - Haukka, Matti

PY - 2018

DA - 2018/01/22

PB - American Chemical Society (ACS)

SP - 930-934

IS - 3

VL - 57

PMID - 29356518

SN - 0020-1669

SN - 1520-510X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Tskhovrebov,

author = {Alexander Tskhovrebov and Anna V. Vasileva and Richard H. Goddard and Tina Riedel and Paul J Dyson and V N Mikhaylov and Tatyana V. Serebryanskaya and V. N. Sorokoumov and Matti Haukka},

title = {Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies.},

journal = {Inorganic Chemistry},

year = {2018},

volume = {57},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/acs.inorgchem.8b00072},

number = {3},

pages = {930--934},

doi = {10.1021/acs.inorgchem.8b00072}

}

MLA

Cite this

MLA Copy

Tskhovrebov, Alexander, et al. “Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies..” Inorganic Chemistry, vol. 57, no. 3, Jan. 2018, pp. 930-934. https://doi.org/10.1021/acs.inorgchem.8b00072.

Publisher

American Chemical Society (ACS)

Journal

Inorganic Chemistry

scimago Q1

wos Q1

SJR

0.958

CiteScore

7.4

Impact factor

4.7

ISSN

00201669 (Print)

1520510X (Electronic)

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