Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation
Igor Stolarov
1
,
Ilya A. Yakushev
1
,
Victor N. Khrustalev
2, 3
,
Alla P Klyagina
1
,
A. B. Kornev
4
,
V.M Martynenko
4
,
Publication type: Journal Article
Publication date: 2018-08-30
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
30160971
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Pd3(OOCMe)6 with indium(III) and gallium(III) acetates was studied to prepare new PdII-based heterometallic carboxylate complexes with group 13 metals. The heterometallic palladium(II)-indium(III) acetate-bridged complexes Pd(OOCMe)4In(OOCMe) (1) and Pd(OOCMe)4In(OOCMe)·MeCOOH (1a) were synthesized and structurally characterized with X-ray crystallography and extended X-ray absorption fine structure in the solid state and solution. A similar Pd-Ga heterometallic complex formed by the reaction of Pd3(OOCMe)6 with gallium(III) acetate in a dilute acetic acid solution, as evidenced by atmospheric pressure chemical ionization mass and UV-vis spectrometry, was unstable at higher concentrations and in the solid state. Complex 1 catalyzes the liquid-phase-selective phenylacetylene and styrene hydrogenation (1 atm of H2 at 20 °C) in acetic acid, ethyl acetate, and N, N-dimethylformamide solutions, while no Pd metal was formed until alkyne and alkene hydrogenation ceased.
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Stolarov I. et al. Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation // Inorganic Chemistry. 2018. Vol. 57. No. 18. pp. 11482-11491.
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Stolarov I., Yakushev I. A., Churakov A. V., Cherkashina N. V., Smirnova N. V., Khramov E. V., Zubavichus Y. V., Khrustalev V. N., Markov A. A., Klyagina A. P., Kornev A. B., Martynenko V., Gekhman A. E., Vargaftik M., Moiseev I. I. Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation // Inorganic Chemistry. 2018. Vol. 57. No. 18. pp. 11482-11491.
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b01313
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01313
TI - Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation
T2 - Inorganic Chemistry
AU - Stolarov, Igor
AU - Yakushev, Ilya A.
AU - Churakov, Andrei V.
AU - Cherkashina, Natalia V.
AU - Smirnova, Nadezhda V.
AU - Khramov, Evgeny V.
AU - Zubavichus, Yan V.
AU - Khrustalev, Victor N.
AU - Markov, Alexander A
AU - Klyagina, Alla P
AU - Kornev, A. B.
AU - Martynenko, V.M
AU - Gekhman, Alexander E.
AU - Vargaftik, Michael
AU - Moiseev, Ilya I
PY - 2018
DA - 2018/08/30
PB - American Chemical Society (ACS)
SP - 11482-11491
IS - 18
VL - 57
PMID - 30160971
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2018_Stolarov,
author = {Igor Stolarov and Ilya A. Yakushev and Andrei V. Churakov and Natalia V. Cherkashina and Nadezhda V. Smirnova and Evgeny V. Khramov and Yan V. Zubavichus and Victor N. Khrustalev and Alexander A Markov and Alla P Klyagina and A. B. Kornev and V.M Martynenko and Alexander E. Gekhman and Michael Vargaftik and Ilya I Moiseev},
title = {Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01313},
number = {18},
pages = {11482--11491},
doi = {10.1021/acs.inorgchem.8b01313}
}
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Stolarov, Igor, et al. “Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation.” Inorganic Chemistry, vol. 57, no. 18, Aug. 2018, pp. 11482-11491. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01313.