Inorganic Chemistry, volume 57, issue 18, pages 11482-11491
Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation
Stolarov Igor
1
,
Yakushev Ilya A.
1
,
Khrustalev Victor N.
2, 3
,
Klyagina Alla P
1
,
Kornev A. B.
4
,
Martynenko V.M
4
,
Publication type: Journal Article
Publication date: 2018-08-30
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Pd3(OOCMe)6 with indium(III) and gallium(III) acetates was studied to prepare new PdII-based heterometallic carboxylate complexes with group 13 metals. The heterometallic palladium(II)-indium(III) acetate-bridged complexes Pd(OOCMe)4In(OOCMe) (1) and Pd(OOCMe)4In(OOCMe)·MeCOOH (1a) were synthesized and structurally characterized with X-ray crystallography and extended X-ray absorption fine structure in the solid state and solution. A similar Pd-Ga heterometallic complex formed by the reaction of Pd3(OOCMe)6 with gallium(III) acetate in a dilute acetic acid solution, as evidenced by atmospheric pressure chemical ionization mass and UV-vis spectrometry, was unstable at higher concentrations and in the solid state. Complex 1 catalyzes the liquid-phase-selective phenylacetylene and styrene hydrogenation (1 atm of H2 at 20 °C) in acetic acid, ethyl acetate, and N, N-dimethylformamide solutions, while no Pd metal was formed until alkyne and alkene hydrogenation ceased.
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5
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5 publications, 31.25%
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Springer Nature
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1 publication, 6.25%
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Royal Society of Chemistry (RSC)
1 publication, 6.25%
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1
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5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Stolarov I. et al. Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation // Inorganic Chemistry. 2018. Vol. 57. No. 18. pp. 11482-11491.
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Stolarov I., Yakushev I. A., Churakov A. V., Cherkashina N. V., Smirnova N. V., Khramov E. V., Zubavichus Y. V., Khrustalev V. N., Markov A. A., Klyagina A. P., Kornev A. B., Martynenko V., Gekhman A. E., Vargaftik M., Moiseev I. I. Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation // Inorganic Chemistry. 2018. Vol. 57. No. 18. pp. 11482-11491.
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b01313
UR - https://doi.org/10.1021%2Facs.inorgchem.8b01313
TI - Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation
T2 - Inorganic Chemistry
AU - Stolarov, Igor
AU - Yakushev, Ilya A.
AU - Churakov, Andrei V.
AU - Cherkashina, Natalia V.
AU - Smirnova, Nadezhda V.
AU - Khramov, Evgeny V.
AU - Zubavichus, Yan V.
AU - Khrustalev, Victor N.
AU - Markov, Alexander A
AU - Klyagina, Alla P
AU - Kornev, A. B.
AU - Martynenko, V.M
AU - Gekhman, Alexander E.
AU - Vargaftik, Michael
AU - Moiseev, Ilya I
PY - 2018
DA - 2018/08/30 00:00:00
PB - American Chemical Society (ACS)
SP - 11482-11491
IS - 18
VL - 57
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2018_Stolarov,
author = {Igor Stolarov and Ilya A. Yakushev and Andrei V. Churakov and Natalia V. Cherkashina and Nadezhda V. Smirnova and Evgeny V. Khramov and Yan V. Zubavichus and Victor N. Khrustalev and Alexander A Markov and Alla P Klyagina and A. B. Kornev and V.M Martynenko and Alexander E. Gekhman and Michael Vargaftik and Ilya I Moiseev},
title = {Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021%2Facs.inorgchem.8b01313},
number = {18},
pages = {11482--11491},
doi = {10.1021/acs.inorgchem.8b01313}
}
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Stolarov, Igor, et al. “Heterometallic Palladium(II)-Indium(III) and -Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation.” Inorganic Chemistry, vol. 57, no. 18, Aug. 2018, pp. 11482-11491. https://doi.org/10.1021%2Facs.inorgchem.8b01313.