Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH
D A Aksyonov
1
,
O. V. Maximova
2, 3
,
Larisa Shvanskaya
2, 3
,
Alexander Vasiliev
2, 3, 4
,
A. A. Tsirlin
5
,
Publication type: Journal Article
Publication date: 2018-12-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
30565920
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two new sodium nickel phosphates, Na5Ni2(PO4)3·H2O (I) and Na6Ni2(PO4)3OH (II), have been synthesized hydrothermally and characterized by synchrotron X-ray diffraction, electron diffraction, low-temperature thermodynamic and magnetic measurements, and ab initio calculations. Unlike the majority of Ni2+ compounds, I and II show predominant ferromagnetic exchange couplings. I crystallizes in the monoclinic space group P21/ n ( a = 14.0395(4) Å, b = 5.1847(14) Å, c = 16.4739(4) Å, β = 110.4186(14)°) and features chains of ferromagnetically coupled Ni2+ ions. In II with the orthorhombic space group Pcmb ( a = 7.5007(15) Å, b = 21.4661(4) Å, c = 7.1732(15) Å), the ferromagnetically coupled Ni2+ ions form dimers arranged on a spin ladder. Both compounds represent rare examples of quasi-one-dimensional ferromagnets. Structural features behind this unusual magnetic behavior are discussed.
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Total citations:
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Citations from 2024:
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Kirsanova M. A. et al. Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH // Inorganic Chemistry. 2018. Vol. 58. No. 1. pp. 610-621.
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Kirsanova M. A., Aksyonov D. A., Maximova O. V., Shvanskaya L., Vasiliev A., Tsirlin A. A., Abakumov A. M. Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH // Inorganic Chemistry. 2018. Vol. 58. No. 1. pp. 610-621.
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b02791
UR - https://doi.org/10.1021/acs.inorgchem.8b02791
TI - Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH
T2 - Inorganic Chemistry
AU - Kirsanova, Maria A
AU - Aksyonov, D A
AU - Maximova, O. V.
AU - Shvanskaya, Larisa
AU - Vasiliev, Alexander
AU - Tsirlin, A. A.
AU - Abakumov, Artem M.
PY - 2018
DA - 2018/12/19
PB - American Chemical Society (ACS)
SP - 610-621
IS - 1
VL - 58
PMID - 30565920
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2018_Kirsanova,
author = {Maria A Kirsanova and D A Aksyonov and O. V. Maximova and Larisa Shvanskaya and Alexander Vasiliev and A. A. Tsirlin and Artem M. Abakumov},
title = {Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH},
journal = {Inorganic Chemistry},
year = {2018},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.inorgchem.8b02791},
number = {1},
pages = {610--621},
doi = {10.1021/acs.inorgchem.8b02791}
}
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MLA
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Kirsanova, Maria A., et al. “Crystal Structures and Low-Dimensional Ferromagnetism of Sodium Nickel Phosphates Na5Ni2(PO4)3·H2O and Na6Ni2(PO4)3OH.” Inorganic Chemistry, vol. 58, no. 1, Dec. 2018, pp. 610-621. https://doi.org/10.1021/acs.inorgchem.8b02791.