Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties
Publication type: Journal Article
Publication date: 2019-02-18
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
30775912
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A luminescence quantum yield of 7.8% was obtained for a quaternary mixed-ligand samarium complex; this value is higher than those previously reported in the literature for such complexes in solution. The complex was prepared by microwave-assisted synthesis in 15 min with a yield of 69%; that is, ∼400 times faster than the usual synthesis that required 4 days and led to a yield of only 30%. Therefore, we propose microwave-assisted synthesis as the method of choice for preparing mixed-ligand lanthanoid complexes.
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35
Total citations:
35
Citations from 2025:
8
(22.86%)
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Melo L. L. L. S., Castro G. P., Gonçalves S. Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties // Inorganic Chemistry. 2019. Vol. 58. No. 5. pp. 3265-3270.
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Melo L. L. L. S., Castro G. P., Gonçalves S. Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties // Inorganic Chemistry. 2019. Vol. 58. No. 5. pp. 3265-3270.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b03340
UR - https://doi.org/10.1021/acs.inorgchem.8b03340
TI - Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties
T2 - Inorganic Chemistry
AU - Melo, Lizandra L L S
AU - Castro, Gerson P
AU - Gonçalves, Simone
PY - 2019
DA - 2019/02/18
PB - American Chemical Society (ACS)
SP - 3265-3270
IS - 5
VL - 58
PMID - 30775912
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2019_Melo,
author = {Lizandra L L S Melo and Gerson P Castro and Simone Gonçalves},
title = {Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.inorgchem.8b03340},
number = {5},
pages = {3265--3270},
doi = {10.1021/acs.inorgchem.8b03340}
}
Cite this
MLA
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Melo, Lizandra L. L. S., et al. “Substantial Intensification of the Quantum Yield of Samarium(III) Complexes by Mixing Ligands: Microwave-Assisted Synthesis and Luminescence Properties.” Inorganic Chemistry, vol. 58, no. 5, Feb. 2019, pp. 3265-3270. https://doi.org/10.1021/acs.inorgchem.8b03340.