From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II)
Publication type: Journal Article
Publication date: 2019-01-30
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
30698431
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The bis(2-pyridylthio)methanidopalladium(II) pincer complex (1), containing a Pd-C bond, was obtained from the reaction of bis(2-pyridylthio)methane (H2L) with palladium(II) acetate in toluene under reflux. When palladium(II) trifluoroacetate was used, H2L reacted to generate the tetrakis(pyridine-2-thiol)palladium(II) complex (2). Complex 2 was converted to a heterobimetallic palladium(II)-iron(II) paddlewheel complex (3) upon treatment with iron(II) triflate in the presence of a base in acetonitrile at room temperature.
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12
Total citations:
12
Citations from 2024:
4
(33%)
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GOST
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Halder P. et al. From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II) // Inorganic Chemistry. 2019. Vol. 58. No. 4. pp. 2270-2274.
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Halder P., SantaLucia D. J., Park S., Berry J. F. From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II) // Inorganic Chemistry. 2019. Vol. 58. No. 4. pp. 2270-2274.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b03568
UR - https://doi.org/10.1021/acs.inorgchem.8b03568
TI - From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II)
T2 - Inorganic Chemistry
AU - Halder, Partha
AU - SantaLucia, Daniel J.
AU - Park, Sungho
AU - Berry, John F.
PY - 2019
DA - 2019/01/30
PB - American Chemical Society (ACS)
SP - 2270-2274
IS - 4
VL - 58
PMID - 30698431
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Halder,
author = {Partha Halder and Daniel J. SantaLucia and Sungho Park and John F. Berry},
title = {From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II)},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.inorgchem.8b03568},
number = {4},
pages = {2270--2274},
doi = {10.1021/acs.inorgchem.8b03568}
}
Cite this
MLA
Copy
Halder, Partha, et al. “From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II).” Inorganic Chemistry, vol. 58, no. 4, Jan. 2019, pp. 2270-2274. https://doi.org/10.1021/acs.inorgchem.8b03568.
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