Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones
Ya-Nan Liu
1
,
Hai-Feng Su
2
,
Yunwu Li
3
,
Qingyun Liu
4
,
Zvonko Jagličić
5
,
Wenguang Wang
1
,
Chen-Ho Tung
1
,
Di Sun
1, 3
Publication type: Journal Article
Publication date: 2019-03-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
30887809
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two novel space craft-like octanuclear Co(II)-silsesquioxane nanocages, {Co8[(MeSiO2)4]2(dmpz)8} (SD/Co8a) and {Co8[(PhSiO2)4]2(dmpz)8} (SD/Co8b) (SD = SunDi; Hdmpz = 3,5-dimethylpyrazole), have been constructed from two similar multidentate silsesquioxane ligands assisted with a pyrazole ligand. The Co8 skeleton consists of eight tetrahedral Co(II) ions arranged in a ring and is further capped by two (MeSiO2)4 ligands up and down. The auxiliary dmpz- ligands seal the ring finally. Electrospray ionization mass spectrometry revealed SD/Co8a and SD/Co8b are highly stable in CH2Cl2. Magnetic analysis implies that SD/Co8a announces antiferromagnetic interactions between Co(II) ions. Moreover, both of them display good homogeneous catalytic activity for hydroboration of ketones in the presence of pinacolborane under mild conditions.
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Liu Y. et al. Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones // Inorganic Chemistry. 2019. Vol. 58. No. 7. pp. 4574-4582.
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Liu Y., Su H., Li Y., Liu Q., Jagličić Z., Wang W., Tung C., Sun D. Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones // Inorganic Chemistry. 2019. Vol. 58. No. 7. pp. 4574-4582.
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TY - JOUR
DO - 10.1021/acs.inorgchem.9b00137
UR - https://doi.org/10.1021/acs.inorgchem.9b00137
TI - Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones
T2 - Inorganic Chemistry
AU - Liu, Ya-Nan
AU - Su, Hai-Feng
AU - Li, Yunwu
AU - Liu, Qingyun
AU - Jagličić, Zvonko
AU - Wang, Wenguang
AU - Tung, Chen-Ho
AU - Sun, Di
PY - 2019
DA - 2019/03/19
PB - American Chemical Society (ACS)
SP - 4574-4582
IS - 7
VL - 58
PMID - 30887809
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2019_Liu,
author = {Ya-Nan Liu and Hai-Feng Su and Yunwu Li and Qingyun Liu and Zvonko Jagličić and Wenguang Wang and Chen-Ho Tung and Di Sun},
title = {Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.inorgchem.9b00137},
number = {7},
pages = {4574--4582},
doi = {10.1021/acs.inorgchem.9b00137}
}
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MLA
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Liu, Ya-Nan, et al. “Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activity for Hydroboration of Ketones.” Inorganic Chemistry, vol. 58, no. 7, Mar. 2019, pp. 4574-4582. https://doi.org/10.1021/acs.inorgchem.9b00137.