Inorganic Chemistry, том 58, издание 10, номера страниц: 7099-7106

Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters.

Pillay Michael N. 1
Liao Jian-Hong 2
Liu C. W. 2
1
 
School of Chemistry and Physics, University of KwaZulu-Natal, Westville campus, Durban 4000, South Africa
2
 
Department of Chemistry, National Dong Hwa University, Hualian 97401, Taiwan, Republic of China
Тип документа
Дата публикации2019-05-02
ИздательAmerican Chemical Society
Название журналаInorganic Chemistry
Квартиль по SCImagoQ1
Квартиль по Web of ScienceQ1
Импакт-фактор 20215.44
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A series of seven luminescent copper(I) dithiophosphonate (dtp) clusters of the type Cu4L4 (L = S2PR(OR')-) were formed from CuCl2·2H2O precursor in aqueous medium under ambient conditions. The dtp ligand serves the dual function of acting as a sacrificial reducing agent and cluster core stabilizer. The new clusters were characterized by 1H and 31P NMR and ESI-MS, and the single-crystal X-ray structures for two representative clusters [Cu4{(S2P(1,4-C6H4OMe)(OR')}4] (R' = OCH(CH3)2; CH2C6H5) were determined. The redox reaction yielded clusters in satisfactory yield, and all exhibited luminescence with λemmax in the range 519-534 nm and half-lives in the range 10-14 μs.
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1. Pillay M. N. и др. Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters // Inorganic Chemistry. 2019. Т. 58. № 10. С. 7099–7106.
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TY - JOUR

DO - 10.1021/acs.inorgchem.9b00783

UR - http://dx.doi.org/10.1021/acs.inorgchem.9b00783

TI - Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters

T2 - Inorganic Chemistry

AU - Pillay, Michael N.

AU - Liao, Jian-Hong

AU - Liu, C. W.

AU - van Zyl, Werner E.

PY - 2019

DA - 2019/05/02

PB - American Chemical Society (ACS)

SP - 7099-7106

IS - 10

VL - 58

SN - 0020-1669

SN - 1520-510X

ER -

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@article{Pillay_2019,

doi = {10.1021/acs.inorgchem.9b00783},

url = {https://doi.org/10.1021%2Facs.inorgchem.9b00783},

year = 2019,

month = {may},

publisher = {American Chemical Society ({ACS})},

volume = {58},

number = {10},

pages = {7099--7106},

author = {Michael N. Pillay and Jian-Hong Liao and C. W. Liu and Werner E. van Zyl},

title = {Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters},

journal = {Inorganic Chemistry}

}

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Pillay, Michael N., et al. “Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters.” Inorganic Chemistry, vol. 58, no. 10, May 2019, pp. 7099–106. Crossref, https://doi.org/10.1021/acs.inorgchem.9b00783.