Inorganic Chemistry, издание 58, том 10, страницы 7099-7106
Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters.
Тип публикации: Journal Article
Дата публикации: 2019-05-02
American Chemical Society (ACS)
Журнал:
Inorganic Chemistry
Квартиль SCImago: Q1
Квартиль WOS: Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A series of seven luminescent copper(I) dithiophosphonate (dtp) clusters of the type Cu4L4 (L = S2PR(OR')-) were formed from CuCl2·2H2O precursor in aqueous medium under ambient conditions. The dtp ligand serves the dual function of acting as a sacrificial reducing agent and cluster core stabilizer. The new clusters were characterized by 1H and 31P NMR and ESI-MS, and the single-crystal X-ray structures for two representative clusters [Cu4{(S2P(1,4-C6H4OMe)(OR')}4] (R' = OCH(CH3)2; CH2C6H5) were determined. The redox reaction yielded clusters in satisfactory yield, and all exhibited luminescence with λemmax in the range 519-534 nm and half-lives in the range 10-14 μs.
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Pillay M. N. et al. Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters. // Inorganic Chemistry. 2019. Vol. 58. No. 10. pp. 7099-7106.
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Pillay M. N., Liao J., Liu C. W., van Zyl W. E. Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters. // Inorganic Chemistry. 2019. Vol. 58. No. 10. pp. 7099-7106.
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TY - JOUR
DO - 10.1021/acs.inorgchem.9b00783
UR - https://doi.org/10.1021/acs.inorgchem.9b00783
TI - Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters.
T2 - Inorganic Chemistry
AU - Liu, C. W.
AU - van Zyl, Werner E.
AU - Pillay, Michael N
AU - Liao, Jian-Hong
PY - 2019
DA - 2019/05/02 00:00:00
PB - American Chemical Society (ACS)
SP - 7099-7106
IS - 10
VL - 58
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2019_Pillay
author = {C. W. Liu and Werner E. van Zyl and Michael N Pillay and Jian-Hong Liao},
title = {Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters.},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.inorgchem.9b00783},
number = {10},
pages = {7099--7106},
doi = {10.1021/acs.inorgchem.9b00783}
}
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Pillay, Michael N., et al. “Aqueous Route to Stable Luminescent Tetranuclear Copper(I) Dithiophosphonate Clusters..” Inorganic Chemistry, vol. 58, no. 10, May. 2019, pp. 7099-7106. https://doi.org/10.1021/acs.inorgchem.9b00783.
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