A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State.
Тип публикации: Journal Article
Дата публикации: 2019-10-16
SCImago Q1
WOS Q1
БС1
SJR: 0.879
CiteScore: 7.5
Impact factor: 4.6
ISSN: 00201669, 1520510X
PubMed ID:
31618013
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A new sublimable dicopper(I) complex bearing 1,2-bis(diphenylphosphino)ethane and 5-trifluoromethyl-3-(2'-pyridyl)pyrazolate ligands has been designed and synthesized, and its crystalline solvated and nonsolvated compounds have also been obtained and investigated. It is shown that only the crystalline solvated compound exhibits reversible and selective luminescence vapochromism, arising from its unique "pyridyl/CH2Cl2/pyridyl" organic sandwich-like stacking arrangement revealed by X-ray crystallography, as supported by time-dependent density functional theory calculations. Additionally, the neutral Cu(I) complex has excellent thermal stability and sublimability, good solid-state luminescence properties, and TADF character, and it is suggested to be a good emitter for vapor-deposited organic light-emitting diodes.
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Chen X. et al. A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State. // Inorganic Chemistry. 2019. Vol. 58. No. 21. pp. 14478-14489.
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Chen X., Yuan H. L., HE L., Chen J., Liu S., Wen H., Zhou G., Wang J., Wong W. A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State. // Inorganic Chemistry. 2019. Vol. 58. No. 21. pp. 14478-14489.
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TY - JOUR
DO - 10.1021/acs.inorgchem.9b01972
UR - https://doi.org/10.1021/acs.inorgchem.9b01972
TI - A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State.
T2 - Inorganic Chemistry
AU - Chen, Xing-Wei
AU - Yuan, Hua Li
AU - HE, LI-HUA
AU - Chen, Jinglin
AU - Liu, Sui-Jun
AU - Wen, Herui
AU - Zhou, Guijiang
AU - Wang, Jin-Yun
AU - Wong, Wai‐Yeung
PY - 2019
DA - 2019/10/16
PB - American Chemical Society (ACS)
SP - 14478-14489
IS - 21
VL - 58
PMID - 31618013
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2019_Chen,
author = {Xing-Wei Chen and Hua Li Yuan and LI-HUA HE and Jinglin Chen and Sui-Jun Liu and Herui Wen and Guijiang Zhou and Jin-Yun Wang and Wai‐Yeung Wong},
title = {A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State.},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.9b01972},
number = {21},
pages = {14478--14489},
doi = {10.1021/acs.inorgchem.9b01972}
}
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MLA
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Chen, Xing-Wei, et al. “A Sublimable Dinuclear Cuprous Complex Showing Selective Luminescence Vapochromism in the Crystalline State..” Inorganic Chemistry, vol. 58, no. 21, Oct. 2019, pp. 14478-14489. https://doi.org/10.1021/acs.inorgchem.9b01972.
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