Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K
Brian De Souza
1
,
Leila Keshavarz
1
,
René R E Steendam
1
,
Olga C Dennehy
2
,
DENIS LYNCH
2
,
Stuart G Collins
2
,
Humphrey Moynihan
2
,
ANITA K. MAGUIRE
3
,
Patrick J Frawley
1
Publication type: Journal Article
Publication date: 2018-03-19
scimago Q2
wos Q2
SJR: 0.449
CiteScore: 4.0
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Abstract
α-Thio-β-chloroacrylamides are of considerable synthetic utility due to their versatile reactivity profile enabling a diverse range of useful transformations. Availability of accurate and extensive solubility data and models is a prerequisite for advanced process optimization of such valuable pure synthetic intermediate compounds, in particular facilitating their isolation with a high degree of efficiency and control. As an illustrative example the solubility of one such derivative, N-(4-methylphenyl-Z-3-chloro-2-(phenylthio)propenamide (Z-1), is described in the present work. Solubility data is reported in 12 pure solvents specifically selected for their potential utility in synthesis and isolation at scale. Solubility data are determined using the gravimetric method across a range of temperatures T= (278.15 to 318.15) K under pressure of 0.1 MPa. On a molar basis, the solubility of Z-1 at temperature T = 298.15 K was observed to follow the order: tetrahydrofuran > 1,2-dichloroethane > 2-methyltetrahydro...
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12
Total citations:
12
Citations from 2024:
1
(8.33%)
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De Souza B. et al. Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K // Journal of Chemical & Engineering Data. 2018. Vol. 63. No. 5. pp. 1419-1428.
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De Souza B., Keshavarz L., Steendam R. R. E., Dennehy O. C., LYNCH D., Collins S. G., Moynihan H., MAGUIRE A. K., Frawley P. J. Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K // Journal of Chemical & Engineering Data. 2018. Vol. 63. No. 5. pp. 1419-1428.
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TY - JOUR
DO - 10.1021/acs.jced.7b01011
UR - https://doi.org/10.1021/acs.jced.7b01011
TI - Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K
T2 - Journal of Chemical & Engineering Data
AU - De Souza, Brian
AU - Keshavarz, Leila
AU - Steendam, René R E
AU - Dennehy, Olga C
AU - LYNCH, DENIS
AU - Collins, Stuart G
AU - Moynihan, Humphrey
AU - MAGUIRE, ANITA K.
AU - Frawley, Patrick J
PY - 2018
DA - 2018/03/19
PB - American Chemical Society (ACS)
SP - 1419-1428
IS - 5
VL - 63
SN - 0021-9568
SN - 1520-5134
ER -
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BibTex (up to 50 authors)
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@article{2018_De Souza,
author = {Brian De Souza and Leila Keshavarz and René R E Steendam and Olga C Dennehy and DENIS LYNCH and Stuart G Collins and Humphrey Moynihan and ANITA K. MAGUIRE and Patrick J Frawley},
title = {Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K},
journal = {Journal of Chemical & Engineering Data},
year = {2018},
volume = {63},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.jced.7b01011},
number = {5},
pages = {1419--1428},
doi = {10.1021/acs.jced.7b01011}
}
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MLA
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De Souza, Brian, et al. “Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K.” Journal of Chemical & Engineering Data, vol. 63, no. 5, Mar. 2018, pp. 1419-1428. https://doi.org/10.1021/acs.jced.7b01011.