Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40
Тип публикации: Journal Article
Дата публикации: 2019-03-13
SCImago Q2
WOS Q2
БС2
SJR: 0.467
CiteScore: 4
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Краткое описание
This paper presents experimental and simulated isobaric heat capacities of the C60(OH)40 fullerenol in the temperature range from T = 0 to 320 K along with the values of standard thermodynamic functions: Sm°, [Φm°(T) – Φm°(0)], and [Hm°(T) – Hm°(0)]. Furthermore, the molar entropy of formation and the molar third law entropy of C60(OH)40 in the crystalline state at T = 298.15 K were calculated. The results of the simultaneous thermal analysis reveal that C60(OH)40 is stable up to 340 K, and further increase of temperature leads to the destruction of the fullerene derivative and the oxidation of the fullerene core.
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Podolsky N. E. et al. Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40 // Journal of Chemical & Engineering Data. 2019. Vol. 64. No. 4. pp. 1480-1487.
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Podolsky N. E., Lelet M. I., Ageev S. V., Novikov A. G., Petrov A., Mazur A., Semenov K. A., Charykov N. A., Vasina L. V., Murin I. Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40 // Journal of Chemical & Engineering Data. 2019. Vol. 64. No. 4. pp. 1480-1487.
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TY - JOUR
DO - 10.1021/acs.jced.8b01075
UR - https://doi.org/10.1021/acs.jced.8b01075
TI - Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40
T2 - Journal of Chemical & Engineering Data
AU - Podolsky, Nikita E
AU - Lelet, M. I.
AU - Ageev, Sergei V
AU - Novikov, Aleksey G
AU - Petrov, Andrey
AU - Mazur, A.
AU - Semenov, Konstantin A.
AU - Charykov, Nikolay A
AU - Vasina, Lubov V
AU - Murin, I.V.
PY - 2019
DA - 2019/03/13
PB - American Chemical Society (ACS)
SP - 1480-1487
IS - 4
VL - 64
SN - 0021-9568
SN - 1520-5134
ER -
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@article{2019_Podolsky,
author = {Nikita E Podolsky and M. I. Lelet and Sergei V Ageev and Aleksey G Novikov and Andrey Petrov and A. Mazur and Konstantin A. Semenov and Nikolay A Charykov and Lubov V Vasina and I.V. Murin},
title = {Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40},
journal = {Journal of Chemical & Engineering Data},
year = {2019},
volume = {64},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.jced.8b01075},
number = {4},
pages = {1480--1487},
doi = {10.1021/acs.jced.8b01075}
}
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Podolsky, Nikita E., et al. “Thermodynamic Properties from Calorimetry and Density Functional Theory and the Thermogravimetric Analysis of the Fullerene Derivative C60(OH)40.” Journal of Chemical & Engineering Data, vol. 64, no. 4, Mar. 2019, pp. 1480-1487. https://doi.org/10.1021/acs.jced.8b01075.
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