“Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air
Publication type: Journal Article
Publication date: 2020-08-18
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
32808522
Organic Chemistry
Abstract
To pursue a highly regioselective and efficient reductive Heck reaction, a series of moisture- and air-stable α-diimine palladium precatalysts were rationally designed, readily synthesized, and fully characterized. The relationship between the structures of the palladium complexes and the catalytic properties was investigated. It was revealed that thebulky-yet-flexiblepalladium complexes allowed highly anti-Markovnikov-selective hydroarylation of alkenes with (hetero)aryl bromides under aerobic conditions. Further synthetic application of the present protocol could provide rapid and straightforward access to functional and biologically active molecules.
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17
Total citations:
17
Citations from 2025:
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(17.65%)
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GOST
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Yang X. W. et al. “Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air // Journal of Organic Chemistry. 2020. Vol. 85. No. 18. pp. 11750-11765.
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Yang X. W., Li D., Song A. X., Liu F. “Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air // Journal of Organic Chemistry. 2020. Vol. 85. No. 18. pp. 11750-11765.
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RIS
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TY - JOUR
DO - 10.1021/acs.joc.0c01509
UR - https://doi.org/10.1021/acs.joc.0c01509
TI - “Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air
T2 - Journal of Organic Chemistry
AU - Yang, Xu Wen
AU - Li, Dong-Hui
AU - Song, A Xiang
AU - Liu, Feng-Shou
PY - 2020
DA - 2020/08/18
PB - American Chemical Society (ACS)
SP - 11750-11765
IS - 18
VL - 85
PMID - 32808522
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Yang,
author = {Xu Wen Yang and Dong-Hui Li and A Xiang Song and Feng-Shou Liu},
title = {“Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air},
journal = {Journal of Organic Chemistry},
year = {2020},
volume = {85},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.joc.0c01509},
number = {18},
pages = {11750--11765},
doi = {10.1021/acs.joc.0c01509}
}
Cite this
MLA
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Yang, Xu Wen, et al. ““Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air.” Journal of Organic Chemistry, vol. 85, no. 18, Aug. 2020, pp. 11750-11765. https://doi.org/10.1021/acs.joc.0c01509.