Journal of Organic Chemistry, volume 86, issue 12, pages 8489-8499
Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates
Publication type: Journal Article
Publication date: 2021-05-28
Journal:
Journal of Organic Chemistry
Q2
Q1
SJR: 0.724
CiteScore: 6.2
Impact factor: 3.3
ISSN: 00223263, 15206904
Organic Chemistry
Abstract
On the basis of the reaction of β-styrylmalonates with furfural derivatives in the presence of GaCl3 that occurs with opening of the furan ring, an efficient diastereoselective method for the synthesis of trisubstituted cyclopentenones containing a 1,4-diketone moiety was developed. The regularities of the reaction were studied, and a number of chemical reactions of the resulting substrates were carried out. A mechanism for the formation of substituted (4-oxo-2-arylcyclopent-2-enyl)malonates was suggested.
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Borisov D. D. et al. Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates // Journal of Organic Chemistry. 2021. Vol. 86. No. 12. pp. 8489-8499.
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Borisov D. D., Chermashentsev G. R., Novikov R. G., Tomilov Y. V. Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates // Journal of Organic Chemistry. 2021. Vol. 86. No. 12. pp. 8489-8499.
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TY - JOUR
DO - 10.1021/acs.joc.1c00536
UR - https://doi.org/10.1021/acs.joc.1c00536
TI - Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates
T2 - Journal of Organic Chemistry
AU - Borisov, Denis D
AU - Chermashentsev, Grigorii R
AU - Novikov, Roman G.
AU - Tomilov, Yury V.
PY - 2021
DA - 2021/05/28
PB - American Chemical Society (ACS)
SP - 8489-8499
IS - 12
VL - 86
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (up to 50 authors)
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@article{2021_Borisov,
author = {Denis D Borisov and Grigorii R Chermashentsev and Roman G. Novikov and Yury V. Tomilov},
title = {Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates},
journal = {Journal of Organic Chemistry},
year = {2021},
volume = {86},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.joc.1c00536},
number = {12},
pages = {8489--8499},
doi = {10.1021/acs.joc.1c00536}
}
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Borisov, Denis D., et al. “Coupling of Styrylmalonates with Furan and Benzofuran Carbaldehydes: Synthesis and Chemistry of Substituted (4-Oxocyclopent-2-enyl)malonates.” Journal of Organic Chemistry, vol. 86, no. 12, May. 2021, pp. 8489-8499. https://doi.org/10.1021/acs.joc.1c00536.
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