Effect of Fluorination of 2,1,3-Benzothiadiazole
Publication type: Journal Article
Publication date: 2015-05-01
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
25901908
Organic Chemistry
Abstract
The 4,7-dithieno-2,1,3-benzothiadiazole (DTBT) moiety and its fluorinated counterpart are important π-conjugated building blocks in the field of organic electronics. Here we present a combined experimental and theoretical investigation into fundamental properties relating to these two molecular entities and discuss the potential impact on extended π-conjugated materials and their electronic properties. While the fluorinated derivative, in the solid state, packs with a cofacial overlap smaller than that of DTBT, we report experimental evidence of stronger optical absorption as well as stronger intra- and intermolecular contacts upon fluorination.
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GOST
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Nielsen C. B. et al. Effect of Fluorination of 2,1,3-Benzothiadiazole // Journal of Organic Chemistry. 2015. Vol. 80. No. 10. pp. 5045-5048.
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Nielsen C. B., White A. C., McCulloch I. Effect of Fluorination of 2,1,3-Benzothiadiazole // Journal of Organic Chemistry. 2015. Vol. 80. No. 10. pp. 5045-5048.
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RIS
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TY - JOUR
DO - 10.1021/acs.joc.5b00430
UR - https://doi.org/10.1021/acs.joc.5b00430
TI - Effect of Fluorination of 2,1,3-Benzothiadiazole
T2 - Journal of Organic Chemistry
AU - Nielsen, C. B.
AU - White, Andrew C
AU - McCulloch, Iain
PY - 2015
DA - 2015/05/01
PB - American Chemical Society (ACS)
SP - 5045-5048
IS - 10
VL - 80
PMID - 25901908
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Nielsen,
author = {C. B. Nielsen and Andrew C White and Iain McCulloch},
title = {Effect of Fluorination of 2,1,3-Benzothiadiazole},
journal = {Journal of Organic Chemistry},
year = {2015},
volume = {80},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.joc.5b00430},
number = {10},
pages = {5045--5048},
doi = {10.1021/acs.joc.5b00430}
}
Cite this
MLA
Copy
Nielsen, C. B., et al. “Effect of Fluorination of 2,1,3-Benzothiadiazole.” Journal of Organic Chemistry, vol. 80, no. 10, May. 2015, pp. 5045-5048. https://doi.org/10.1021/acs.joc.5b00430.