In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides
Publication type: Journal Article
Publication date: 2016-06-07
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
27267071
Organic Chemistry
Abstract
A mild approach for direct C2 sulfonylation of heteroaromatic N-oxides with sulfonyl hydrazides affording 2-sulfonyl quinolines/pyridines has been developed. A variety of heteroaromatic N-oxides and sulfonyl hydrazides participate effectively in this transformation which uses hypoiodites (generated in situ from NaI and TBHP) as a means of substrate activators. In this reaction, the N-oxide plays a dual role, acting as a traceless directing group as well as a source of oxygen atom.
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Citations from 2024:
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GOST
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SU Y. et al. In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides // Journal of Organic Chemistry. 2016. Vol. 81. No. 12. pp. 4981-4987.
GOST all authors (up to 50)
Copy
SU Y., Zhou X., He C., Zhang W., Xiao L., Xiao X. In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides // Journal of Organic Chemistry. 2016. Vol. 81. No. 12. pp. 4981-4987.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.joc.6b00475
UR - https://doi.org/10.1021/acs.joc.6b00475
TI - In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides
T2 - Journal of Organic Chemistry
AU - SU, YUAN
AU - Zhou, Xuejun
AU - He, Chunlian
AU - Zhang, Wei
AU - Xiao, Ling
AU - Xiao, Xia
PY - 2016
DA - 2016/06/07
PB - American Chemical Society (ACS)
SP - 4981-4987
IS - 12
VL - 81
PMID - 27267071
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_SU,
author = {YUAN SU and Xuejun Zhou and Chunlian He and Wei Zhang and Ling Xiao and Xia Xiao},
title = {In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides},
journal = {Journal of Organic Chemistry},
year = {2016},
volume = {81},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.joc.6b00475},
number = {12},
pages = {4981--4987},
doi = {10.1021/acs.joc.6b00475}
}
Cite this
MLA
Copy
SU, YUAN, et al. “In Situ Generated HypoIodite Activator for the C2 Sulfonylation of Heteroaromatic N-oxides.” Journal of Organic Chemistry, vol. 81, no. 12, Jun. 2016, pp. 4981-4987. https://doi.org/10.1021/acs.joc.6b00475.