Journal of Organic Chemistry, volume 81, issue 20, pages 9992-10001
Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis
3
Department
of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409, United States
|
Publication type: Journal Article
Publication date: 2016-09-30
Journal:
Journal of Organic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Abstract
We report the first example of difluoroalkylation/C-H annulation cascade reactions of cyclopropyl olefins induced by visible-light photoredox catalysis regioselectively affording partially hydrogenated naphthalenes and quinolines with a variety of difluorinated side chains. The alkylation reagent could be extended to monofluoro and trifluoro reagents, nitrile and malonate. The regioselectivity was investigated by means of density functional theory calculations.
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Citations by publishers
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20
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Royal Society of Chemistry (RSC)
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19 publications, 35.19%
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1 publication, 1.85%
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1 publication, 1.85%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Li J. et al. Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis // Journal of Organic Chemistry. 2016. Vol. 81. No. 20. pp. 9992-10001.
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Li J., Chen J., Jiao W., Wang G., Cao Y., Cheng X., Li G. Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis // Journal of Organic Chemistry. 2016. Vol. 81. No. 20. pp. 9992-10001.
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TY - JOUR
DO - 10.1021/acs.joc.6b01825
UR - https://doi.org/10.1021/acs.joc.6b01825
TI - Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis
T2 - Journal of Organic Chemistry
AU - Chen, Jingzhi
AU - Jiao, Wei
AU - Li, Jin
AU - Wang, Guoqiang
AU - Cao, Yi
AU - Cheng, Xu
AU - Li, Guigen
PY - 2016
DA - 2016/09/30 00:00:00
PB - American Chemical Society (ACS)
SP - 9992-10001
IS - 20
VL - 81
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2016_Li,
author = {Jingzhi Chen and Wei Jiao and Jin Li and Guoqiang Wang and Yi Cao and Xu Cheng and Guigen Li},
title = {Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis},
journal = {Journal of Organic Chemistry},
year = {2016},
volume = {81},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.joc.6b01825},
number = {20},
pages = {9992--10001},
doi = {10.1021/acs.joc.6b01825}
}
Cite this
MLA
Copy
Li, Jin, et al. “Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis.” Journal of Organic Chemistry, vol. 81, no. 20, Sep. 2016, pp. 9992-10001. https://doi.org/10.1021/acs.joc.6b01825.