Journal of Organic Chemistry, volume 82, issue 14, pages 7394-7401

Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes

Yu Liu 1
Qiao-Lin Wang 1
Cong-Shan Zhou 1
Bi Quan Xiong 1
Pan Liang Zhang 1
Chang An Yang 1
Ke Wen Tang 1
Publication typeJournal Article
Publication date2017-06-28
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor3.6
ISSN00223263, 15206904
Organic Chemistry
Abstract
A novel metal-free oxidative ring-opening/cyclization of methylenecyclopropanes with ethers was established for the synthesis of diverse 2-substituted 3,4-dihydronaphthalenes with high selectivity and efficiency. This oxidative cyclization is achieved by C(sp3)-H functionalization, ring-opening, and cyclization, and this method represents a new example of methylenecyclopropane oxidative cyclization with an aromatic carbon and a C(sp3)-H bond by simultaneously forming two new carbon-carbon bonds.

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GOST |
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GOST Copy
Liu Yu. et al. Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes // Journal of Organic Chemistry. 2017. Vol. 82. No. 14. pp. 7394-7401.
GOST all authors (up to 50) Copy
Liu Yu., Wang Q., Zhou C., Xiong B. Q., Zhang P. L., Yang C. A., Tang K. W. Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes // Journal of Organic Chemistry. 2017. Vol. 82. No. 14. pp. 7394-7401.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.joc.7b00970
UR - https://doi.org/10.1021/acs.joc.7b00970
TI - Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes
T2 - Journal of Organic Chemistry
AU - Wang, Qiao-Lin
AU - Zhou, Cong-Shan
AU - Xiong, Bi Quan
AU - Zhang, Pan Liang
AU - Yang, Chang An
AU - Tang, Ke Wen
AU - Liu, Yu
PY - 2017
DA - 2017/06/28 00:00:00
PB - American Chemical Society (ACS)
SP - 7394-7401
IS - 14
VL - 82
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Liu,
author = {Qiao-Lin Wang and Cong-Shan Zhou and Bi Quan Xiong and Pan Liang Zhang and Chang An Yang and Ke Wen Tang and Yu Liu},
title = {Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes},
journal = {Journal of Organic Chemistry},
year = {2017},
volume = {82},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.joc.7b00970},
number = {14},
pages = {7394--7401},
doi = {10.1021/acs.joc.7b00970}
}
MLA
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MLA Copy
Liu, Yu., et al. “Metal-Free Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes.” Journal of Organic Chemistry, vol. 82, no. 14, Jun. 2017, pp. 7394-7401. https://doi.org/10.1021/acs.joc.7b00970.
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