N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications.
Publication type: Journal Article
Publication date: 2018-01-19
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
29302964
Organic Chemistry
Abstract
N-Thiocyanatosaccharin (R1) was readily prepared from the sweet additive Saccharin in two steps with a 71% overall yield. By applying this new reagent to diverse nucleophiles such as benzothiophenes, indoles, oxindoles, aromatic amines, phenols, β-keto carbonyl compounds, and aromatic ketones, a novel electrophilic thiocyanation reaction was achieved with high yields (up to 99%). The potential recycling of Saccharin, the wide scope of substrates, and the mild reaction conditions made this protocol much more practical.
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104
Total citations:
104
Citations from 2025:
11
(10.58%)
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MLA
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GOST
Copy
Wu D. et al. N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications. // Journal of Organic Chemistry. 2018. Vol. 83. No. 3. pp. 1576-1583.
GOST all authors (up to 50)
Copy
Wu D., Qiu J., Karmaker P. G., Yin H., Chen F. N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications. // Journal of Organic Chemistry. 2018. Vol. 83. No. 3. pp. 1576-1583.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.joc.7b02850
UR - https://doi.org/10.1021/acs.joc.7b02850
TI - N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications.
T2 - Journal of Organic Chemistry
AU - Wu, Di
AU - Qiu, Jiashen
AU - Karmaker, Pran Gopal
AU - Yin, Hongquan
AU - Chen, Fuxue
PY - 2018
DA - 2018/01/19
PB - American Chemical Society (ACS)
SP - 1576-1583
IS - 3
VL - 83
PMID - 29302964
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Wu,
author = {Di Wu and Jiashen Qiu and Pran Gopal Karmaker and Hongquan Yin and Fuxue Chen},
title = {N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications.},
journal = {Journal of Organic Chemistry},
year = {2018},
volume = {83},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.joc.7b02850},
number = {3},
pages = {1576--1583},
doi = {10.1021/acs.joc.7b02850}
}
Cite this
MLA
Copy
Wu, Di, et al. “N-Thiocyanatosaccharin: A "Sweet" Electrophilic Thiocyanation Reagent and the Synthetic Applications..” Journal of Organic Chemistry, vol. 83, no. 3, Jan. 2018, pp. 1576-1583. https://doi.org/10.1021/acs.joc.7b02850.