Journal of Organic Chemistry, volume 83, issue 8, pages 4657-4664
Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes
Publication type: Journal Article
Publication date: 2018-03-27
Journal:
Journal of Organic Chemistry
Q2
Q1
SJR: 0.724
CiteScore: 6.2
Impact factor: 3.3
ISSN: 00223263, 15206904
Organic Chemistry
Abstract
A new FeCl2- and DTBP (di- tert-butyl peroxide)-promoted oxidative ring-opening and cyclization of methylenecyclopropanes with aldehydes for the synthesis of 2-acyl-3,4-dihydronaphthalenes is presented. This oxidative cyclization reaction proceeds via a radical addition, ring-opening, and cyclization sequence facilitated by a Lewis acid, and it offers a practical and straightforward route for the oxidative cyclization of methylenecyclopropanes with an aromatic carbon and a C(sp2)-H bond by simultaneously forming two new carbon-carbon bonds.
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GOST
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Liu Yu. et al. Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes // Journal of Organic Chemistry. 2018. Vol. 83. No. 8. pp. 4657-4664.
GOST all authors (up to 50)
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Liu Yu., Wang Q., Zhou C., Xiong B., Zhang P. L., Yang C. A., Tang K. Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes // Journal of Organic Chemistry. 2018. Vol. 83. No. 8. pp. 4657-4664.
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TY - JOUR
DO - 10.1021/acs.joc.8b00427
UR - https://doi.org/10.1021/acs.joc.8b00427
TI - Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes
T2 - Journal of Organic Chemistry
AU - Liu, Yu
AU - Wang, Qiao-Lin
AU - Zhou, Cong-Shan
AU - Xiong, Biquan
AU - Zhang, Pan Liang
AU - Yang, Chang An
AU - Tang, Kewen
PY - 2018
DA - 2018/03/27
PB - American Chemical Society (ACS)
SP - 4657-4664
IS - 8
VL - 83
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (up to 50 authors)
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@article{2018_Liu,
author = {Yu Liu and Qiao-Lin Wang and Cong-Shan Zhou and Biquan Xiong and Pan Liang Zhang and Chang An Yang and Kewen Tang},
title = {Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes},
journal = {Journal of Organic Chemistry},
year = {2018},
volume = {83},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.joc.8b00427},
number = {8},
pages = {4657--4664},
doi = {10.1021/acs.joc.8b00427}
}
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Liu, Yu., et al. “Oxidative C–C Bond Functionalization of Methylenecyclopropanes with Aldehydes for the Formation of 2-Acyl-3,4-dihydronaphthalenes.” Journal of Organic Chemistry, vol. 83, no. 8, Mar. 2018, pp. 4657-4664. https://doi.org/10.1021/acs.joc.8b00427.