Journal of Organic Chemistry, volume 83, issue 15, pages 8780-8785
Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one
Publication type: Journal Article
Publication date: 2018-06-19
Journal:
Journal of Organic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Abstract
A Cu-catalyzed three-component cascade cyclization among 2-formylbenzonitrile, cyclopropyl ketones, and diaryliodonium salts for the construction of fused isoindolin-1-one compounds is achieved. Pentacyclic isoindolinone derivatives could be obtained in moderate to good yields. The proposed mechanism involved a ring expansion of cyclopropyl ketones/formation of N-acyliminium/hetero-[4 + 2]-cycloaddition process.
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- We do not take into account publications without a DOI.
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Li J. et al. Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one // Journal of Organic Chemistry. 2018. Vol. 83. No. 15. pp. 8780-8785.
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Li J., Bai S., Li Y., Wang Z., Huo X., Liu L. Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one // Journal of Organic Chemistry. 2018. Vol. 83. No. 15. pp. 8780-8785.
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TY - JOUR
DO - 10.1021/acs.joc.8b01120
UR - https://doi.org/10.1021/acs.joc.8b01120
TI - Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one
T2 - Journal of Organic Chemistry
AU - Bai, Shuhua
AU - Wang, Zhengbing
AU - Huo, Xiaoyu
AU - Li, Jian
AU - Li, Yang
AU - Liu, Li
PY - 2018
DA - 2018/06/19 00:00:00
PB - American Chemical Society (ACS)
SP - 8780-8785
IS - 15
VL - 83
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2018_Li,
author = {Shuhua Bai and Zhengbing Wang and Xiaoyu Huo and Jian Li and Yang Li and Li Liu},
title = {Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one},
journal = {Journal of Organic Chemistry},
year = {2018},
volume = {83},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.joc.8b01120},
number = {15},
pages = {8780--8785},
doi = {10.1021/acs.joc.8b01120}
}
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Li, Jian, et al. “Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N-acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one.” Journal of Organic Chemistry, vol. 83, no. 15, Jun. 2018, pp. 8780-8785. https://doi.org/10.1021/acs.joc.8b01120.