Journal of Organic Chemistry

, том 83 , издание 22 , страницы 14010-14021

Intramolecular Palladium-Catalyzed Oxidative Amination of Furans: Synthesis of Functionalized Indoles.

Тип публикации: Journal Article

Дата публикации: 2018-10-22

American Chemical Society (ACS)

Journal of Organic Chemistry

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SJR: 0.737

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00223263, 15206904

DOI: 10.1021/acs.joc.8b02470

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PubMed ID: 30346172

Organic Chemistry

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Unconventional modification of palladium-catalyzed oxidative amination where a furan ring serves as a masked olefin is described. The designed chemical process provides 2-(2-acylvinyl)indole derivatives with up to a 93% yield and excellent E-selectivity. A highly reactive α,β-unsaturated carbonyl moiety of the obtained compounds allows for accessing various heteroaromatic scaffolds through simple synthetic procedures.

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Makarov A. S., Uchuskin M. G., Gevorgyan V. Intramolecular Palladium-Catalyzed Oxidative Amination of Furans: Synthesis of Functionalized Indoles. // Journal of Organic Chemistry. 2018. Vol. 83. No. 22. pp. 14010-14021.

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TY - JOUR

DO - 10.1021/acs.joc.8b02470

UR - https://pubs.acs.org/doi/10.1021/acs.joc.8b02470

TI - Intramolecular Palladium-Catalyzed Oxidative Amination of Furans: Synthesis of Functionalized Indoles.

T2 - Journal of Organic Chemistry

AU - Makarov, Anton S

AU - Uchuskin, Maxim G

AU - Gevorgyan, Vladimir

PY - 2018

DA - 2018/10/22

PB - American Chemical Society (ACS)

SP - 14010-14021

IS - 22

VL - 83

PMID - 30346172

SN - 0022-3263

SN - 1520-6904

ER -

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@article{2018_Makarov,

author = {Anton S Makarov and Maxim G Uchuskin and Vladimir Gevorgyan},

title = {Intramolecular Palladium-Catalyzed Oxidative Amination of Furans: Synthesis of Functionalized Indoles.},

journal = {Journal of Organic Chemistry},

year = {2018},

volume = {83},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://pubs.acs.org/doi/10.1021/acs.joc.8b02470},

number = {22},

pages = {14010--14021},

doi = {10.1021/acs.joc.8b02470}

}

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Makarov, Anton S., et al. “Intramolecular Palladium-Catalyzed Oxidative Amination of Furans: Synthesis of Functionalized Indoles..” Journal of Organic Chemistry, vol. 83, no. 22, Oct. 2018, pp. 14010-14021. https://pubs.acs.org/doi/10.1021/acs.joc.8b02470.